Lithium tetrachloroaurate

Base Information

• Chemical Name: Lithium tetrachloroaurate
• CAS No.: 3145-91-3
• Molecular Formula: AuCl4 . Li
• Molecular Weight: 345.719
• DSSTox Substance ID: DTXSID60584351
• Wikidata: Q4456676
• Mol file: 3145-91-3.mol

Synonyms:lithium tetrachloroaurate;3145-91-3;lithium;tetrachlorogold(1-);Lithium tetrachloroaurate(III) hydrate;Lithium tetrachloroaurate(1-);DTXSID60584351;Lithium tetrachloroaurate(III), 99.995%;Q4456676

Chemical Property of Lithium tetrachloroaurate

Chemical Property:

• PSA: 0.00000
• LogP: -11.98650
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 345.855034
• Heavy Atom Count: 6
• Complexity: 19.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Lithium tetrachloroaurate(III) 99.995% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Li+].Cl[Au-](Cl)(Cl)Cl

Technology Process of Lithium tetrachloroaurate

There total 17 articles about Lithium tetrachloroaurate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trichloro(4-cyanopyridine)gold(III) (14038-56-3) + lithium chloride → pyridine-4-carbonitrile (100-48-1) + lithium tetrachloroaurate (3145-91-3)

Guidance literature:

In methanol; dichloromethane; water; addn. of Au-complex in dichloromethane to LiCl+HClO4 in methanol:water (95:5 v/v) at 25 °C; detected by UV; Kinetics;

DOI:10.1039/DT9910000307

Reference yield:

trichloro(2,4-dimethylthiazole)gold(III) (132963-53-2) + lithium chloride → 2,4-dimethylthiazole (541-58-2) + lithium tetrachloroaurate (3145-91-3)

Guidance literature:

In methanol; dichloromethane; water; addn. of Au-complex in dichloromethane to LiCl+HClO4 in methanol:water (95:5 v/v) at 25 °C; detected by UV; Kinetics;

DOI:10.1039/DT9910000307

Reference yield:

trichloro(2-methylbenzoselenazole)gold(III) (132963-46-3) + lithium chloride → 2-methylbenzoselenazole (2818-88-4) + lithium tetrachloroaurate (3145-91-3)

Guidance literature:

In methanol; dichloromethane; water; addn. of Au-complex in dichloromethane to LiCl+HClO4 in methanol:water (95:5 v/v) at 25 °C; detected by UV; Kinetics;

DOI:10.1039/DT9910000307

upstream raw materials:

trichloro(pyridine)gold(III)

trichloro(oxazole)gold(III)

trichloro(thiazole)gold(III)

Au(Cl)3(C₄H₅NS)

Downstream raw materials:

gold

C₅H₄N(N₂)C₆H₄NLiC(N(CH₃)2)2⁽¹⁺⁾*AuCl₄^(1-)={C₅H₄N(N₂)C₆H₄NLiC(N(CH₃)2)2}{AuCl₄}

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