Trichloro(pyridine)gold(III)

Base Information

• Chemical Name: Trichloro(pyridine)gold(III)
• CAS No.: 14911-01-4
• Molecular Formula: C5H5 Au Cl3 N
• Molecular Weight: 382.427
• European Community (EC) Number: 623-895-5
• Mol file: 14911-01-4.mol

Synonyms:Trichloro(pyridine)gold(III);SCHEMBL10404373;AMY11756;Trichloro(pyridine)gold(III), 97%;SC10719;(PYRIDINE)GOLD TRICHLORIDE;TRICHLORO(PYRIDINE)GOLD(III);Trichloropyridinegold(III)

Chemical Property of Trichloro(pyridine)gold(III)

Chemical Property:

• Vapor Pressure: 22.8mmHg at 25°C
• Melting Point: 232-240 °C
• Boiling Point: 115.3°Cat760mmHg
• Flash Point: 20°C
• PSA: 12.89000
• Density: g/cm³
• LogP: 3.14760
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 380.915327
• Heavy Atom Count: 10
• Complexity: 38.9

Purity/Quality:

99%, ^*data from raw suppliers

Trichloropyridinegold(III), min. 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=NC=C1.Cl[Au](Cl)Cl

Technology Process of Trichloro(pyridine)gold(III)

There total 9 articles about Trichloro(pyridine)gold(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

pyridine (110-86-1) + potassium tetrachloroaurate(III) dihydrate → trichloro(pyridine)gold(III) (14911-01-4)

Guidance literature:

In water; KAuCl4*2H2O in H2O treated dropwise with stoich. amount of nitrogen donor base in H2O under stirring, pptd.; ppt. filtered off, washed (H2O) 3 times, dried (vac.), elem. anal.;

DOI:10.1002/ejic.200700457

Reference yield: 82.0%

gold(III) chloride (13453-07-1) → Au(py)Cl3 (14911-01-4)

Guidance literature:

With C₅H₅N; In water; AuCl3 was dissolved in H2O and pyridine was added with stirring;; the ppt. was dried under vacuum;;

DOI:10.1016/S0020-1693(00)87574-X

Reference yield: 75.5%

pyridine (110-86-1) + gold(III) tetrachloride trihydrate → trichloro(pyridine)gold(III) (14911-01-4)

Guidance literature:

In water;

DOI:10.1080/00958972.2013.773428

upstream raw materials:

gold

gold(III) chloride

pyridine

{Au(CH₂P(S)(C₆H₅)2)}2

Downstream raw materials:

pyridine

lithium tetrachloroaurate

{Au₂(CH₂P(S)(C₆H₅)2)2Cl₂}

{Au(CH₂P(S)(C₆H₅)2)Cl}2

Refernces

• 1、 Canty, Allan J.,Minchin, Nigel J.,Healy, Peter C.,White, Allan H.. "Co-ordination Chemistry of Dimethylgold(III). Synthesis, Spectroscopic, and Structural Studies of Complexes With Neutral Aromatic Nitrogen-donor Ligands". . p. 1795 - 1802. Retrieved 1982.
• 2、 Pitteri, Bruno,Bortoluzzi, Marco. "Displacement of neutral nitrogen donors by chloride in AuCl3(am) (am = pyridines and amines): Kinetics and DFT calculations show the effects of basicity and π-acceptor ability". . p. 4456 - 4461. Retrieved 2008/03/12.