dicarbonyl(bis(2-diphenylphosphinoethyl)phenylphosphine)ruthenium

Base Information

Chemical Name:dicarbonyl(bis(2-diphenylphosphinoethyl)phenylphosphine)ruthenium
CAS No.:97932-51-9
Molecular Formula:C₃₆H₃₃O₂P₃Ru
Molecular Weight:691.648
Hs Code.:

Synonyms:dicarbonyl(bis(2-diphenylphosphinoethyl)phenylphosphine)ruthenium

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Chemical Property of dicarbonyl(bis(2-diphenylphosphinoethyl)phenylphosphine)ruthenium

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Technology Process of dicarbonyl(bis(2-diphenylphosphinoethyl)phenylphosphine)ruthenium

There total 1 articles about dicarbonyl(bis(2-diphenylphosphinoethyl)phenylphosphine)ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 23582-02-7
bis(2-diphenylphosphinoethyl)phenylphosphine

: 97932-51-9
dicarbonyl(bis(2-diphenylphosphinoethyl)phenylphosphine)ruthenium

Guidance literature:: In toluene; under Ar; soln. of Ru3(CO)12 and triphosphane in toluene refluxed for 4.5 h; concd., hexane added, mixt. stored overnight at 273 K, crystals filteredoff, washed with hexane, dried in vacuo;
DOI:10.1021/om049729x

Reference yield: 88.0%

: 97932-51-9
dicarbonyl(bis(2-diphenylphosphinoethyl)phenylphosphine)ruthenium

: RuI(CO)2(C₆H₅P(CH₂CH₂P(C₆H₅)2)2)⁽¹⁺⁾*I^(1-)=(RuI(CO)2(C₆H₅P(CH₂CH₂P(C₆H₅)2)2))I

Guidance literature:: With I₂; In benzene; slow addn. of I2 in benzene to a soln. of Ru-compd. in benzene, stirring for 30 min; filtn., washing with benzene and ether, drying under vac. overnight, elem. anal.;
DOI:10.1016/S0020-1693(00)86781-X

Reference yield: 79.0%

: 97932-51-9
dicarbonyl(bis(2-diphenylphosphinoethyl)phenylphosphine)ruthenium

: Ru(CH₃)(CO)2(C₆H₅P(CH₂CH₂P(C₆H₅)2)2)⁽¹⁺⁾*I^(1-)=(Ru(CH₃)(CO)2(C₆H₅P(CH₂CH₂P(C₆H₅)2)2))I

Guidance literature:: With CH₃I; In benzene; stirring of a mixt. of Ru-compd. and of MeI in benzene for 6 h (under Ar, Schlenk app.); filtn., washing with benzene and ether, drying under vac. overnight, elem. anal.;
DOI:10.1016/S0020-1693(00)86781-X