(Z)-But-2-enedioic acid mono-((S)-1-phenyl-ethyl) ester

Base Information

Chemical Name:(Z)-But-2-enedioic acid mono-((S)-1-phenyl-ethyl) ester
CAS No.:165304-73-4
Molecular Formula:C₁₂H₁₂O₄
Molecular Weight:220.225
Hs Code.:

Synonyms:(Z)-But-2-enedioic acid mono-((S)-1-phenyl-ethyl) ester

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Chemical Property of (Z)-But-2-enedioic acid mono-((S)-1-phenyl-ethyl) ester

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Technology Process of (Z)-But-2-enedioic acid mono-((S)-1-phenyl-ethyl) ester

There total 1 articles about (Z)-But-2-enedioic acid mono-((S)-1-phenyl-ethyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-31-6
maleic anhydride

: 1445-91-6
(S)-1-phenylethanol

: 165304-73-4
(Z)-But-2-enedioic acid mono-((S)-1-phenyl-ethyl) ester

Guidance literature:: In toluene; Heating;
DOI:10.1021/ja00093a013

Reference yield:

: 165304-73-4
(Z)-But-2-enedioic acid mono-((S)-1-phenyl-ethyl) ester

: 162362-11-0
(1S,2R,3S,4R)-Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid mono-((S)-1-phenyl-ethyl) ester

Guidance literature:: Multi-step reaction with 3 steps

1: conc. H₂SO₄ / CH₂Cl₂ / Ambient temperature

2: BF₃*OEt₂ / CH₂Cl₂ / 1 h / -78 °C

3: 91 percent / CF₃CO₂H / CH₂Cl₂ / 24 h / Ambient temperature

With sulfuric acid; boron trifluoride diethyl etherate; trifluoroacetic acid; In dichloromethane;
DOI:10.1021/ja00093a013

Reference yield:

: 165304-73-4
(Z)-But-2-enedioic acid mono-((S)-1-phenyl-ethyl) ester

: (1S,2S,3S,4R)-Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid mono-((S)-1-phenyl-ethyl) ester

Guidance literature:: Multi-step reaction with 4 steps

1: conc. H₂SO₄ / CH₂Cl₂ / Ambient temperature

2: BF₃*OEt₂ / CH₂Cl₂ / 1 h / -78 °C

3: 91 percent / CF₃CO₂H / CH₂Cl₂ / 24 h / Ambient temperature

4: LDA / tetrahydrofuran / 0.5 h / -78 °C

With sulfuric acid; boron trifluoride diethyl etherate; trifluoroacetic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00093a013