1-formyl-2,2′,3,3′,4,4′5,5′-octamethylferrocene

Base Information

• Chemical Name: 1-formyl-2,2′,3,3′,4,4′5,5′-octamethylferrocene
• CAS No.: 128925-12-2
• Molecular Formula: C₁₉H₂₆FeO
• Molecular Weight: 326.262
• Mol file: 128925-12-2.mol

Synonyms:1-formyl-2,2′,3,3′,4,4′5,5′-octamethylferrocene

Chemical Property of 1-formyl-2,2′,3,3′,4,4′5,5′-octamethylferrocene

Chemical Property:

Purity/Quality:

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MSDS Files:

Useful:

Technology Process of 1-formyl-2,2′,3,3′,4,4′5,5′-octamethylferrocene

There total 2 articles about 1-formyl-2,2′,3,3′,4,4′5,5′-octamethylferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,1',2,2',3,3',4,4'-octamethylferrocene (59568-28-4) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → 1-formyl-2,2′,3,3′,4,4′5,5′-octamethylferrocene (128925-12-2)

Guidance literature:

With phosphorus oxytrichloride; In chloroform; Ar; stirring; 50-60°C; 6 h;; poured into water at room temp.; extd. with Et2O; washed with water and saturated NaCl soln.; dried over Na2SO4; evapd.; elem. anal.;;

DOI:10.1021/ja00177a020

Reference yield: 83.0%

1,1',2,2',3,3',4,4'-octamethylferrocene (59568-28-4) + sodium acetate (127-09-3) → 1-formyl-2,2′,3,3′,4,4′5,5′-octamethylferrocene (128925-12-2)

Guidance literature:

With POCl₃; In water; N,N-dimethyl-formamide; stirring (room temp., 1 h, refluxing, 2 h), NaOAc soln. (H2O) addn. (0°C), stirring (6 h); extg. (Et2O), washing (1 M HCl, NaHCO3 soln., brine), drying (MgSO4), evapn., recrystn. (Et2O); elem. anal.;

DOI:10.1021/om9609978

Reference yield: 83.0%

1-formyl-2,2′,3,3′,4,4′5,5′-octamethylferrocene (128925-12-2) + Diethyl 4-[bis(2,3,4,5,6-pentachlorophenyl)methyl]-2,3,5,6-tetrachlorobenzyl phosphonate (329897-50-9) → C39H28Cl14Fe (1425938-44-8)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at -78 ℃;

DOI:10.1021/cm400147p

upstream raw materials:

1,1',2,2',3,3',4,4'-octamethylferrocene

N,N-dimethyl-formamide

sodium acetate

Downstream raw materials:

C₃₉H₂₈Cl₁₄Fe