Furan, tetrahydro-3-methyl-5-(1-methylethyl)-2-(2-propenyl)-, (2R,3S,5S)-rel- (9CI)

Base Information

Chemical Name:Furan, tetrahydro-3-methyl-5-(1-methylethyl)-2-(2-propenyl)-, (2R,3S,5S)-rel- (9CI)
CAS No.:243983-03-1
Molecular Formula:C₁₁H₂₀O
Molecular Weight:168.279
Hs Code.:
Mol file:243983-03-1.mol

Synonyms:Furan,tetrahydro-3-methyl-5-(1-methylethyl)-2-(2-propenyl)-, (2R,3S,5S)-rel- (9CI)

Suppliers and Price of Furan, tetrahydro-3-methyl-5-(1-methylethyl)-2-(2-propenyl)-, (2R,3S,5S)-rel- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Furan, tetrahydro-3-methyl-5-(1-methylethyl)-2-(2-propenyl)-, (2R,3S,5S)-rel- (9CI)

Chemical Property:

PSA：0.00000
LogP:0.00000

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Furan, tetrahydro-3-methyl-5-(1-methylethyl)-2-(2-propenyl)-, (2R,3S,5S)-rel- (9CI)

There total 4 articles about Furan, tetrahydro-3-methyl-5-(1-methylethyl)-2-(2-propenyl)-, (2R,3S,5S)-rel- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: (2S*,4S*)-1-acetoxy-4-isopropyl-2-methyl-tetrahydrofuran

: 762-72-1
allyl-trimethyl-silane

: 243983-04-2,243983-03-1
(2S*,4S*)-1-allyl-4-isopropyl-2-methyl-tetrahydrofuran

Guidance literature:: With stannic bromide; In dichloromethane; at -78 - 25 ℃; for 2h;
DOI:10.1016/S0040-4020(99)00441-X

Reference yield: 39.0%

: (2S*,4R*)-1-acetoxy-4-isopropyl-2-methyl-tetrahydrofuran

: 762-72-1
allyl-trimethyl-silane

: 243983-04-2,243983-03-1
(2S*,4R*)-1-allyl-4-isopropyl-2-methyl-tetrahydrofuran

Guidance literature:: With stannic bromide; In dichloromethane; at -78 - 25 ℃; for 2h;
DOI:10.1016/S0040-4020(99)00441-X

Reference yield:

: 89065-56-5,89065-57-6
cis-4-isopropyl-2-methyl-butyrolactone

: 243983-04-2,243983-03-1
(2S*,4S*)-1-allyl-4-isopropyl-2-methyl-tetrahydrofuran

Guidance literature:: Multi-step reaction with 2 steps

1.1: DIBAL / CH₂Cl₂ / 1 h / -78 °C

1.2: 85 percent / DMAP; pyridine / CH₂Cl₂ / 10 h

2.1: 69 percent / SnBr₄ / CH₂Cl₂ / 2 h / -78 - 25 °C

With stannic bromide; diisobutylaluminium hydride; In dichloromethane; 1.1: Reduction / 1.2: Acetylation / 2.1: Condensation;
DOI:10.1016/S0040-4020(99)00441-X