(Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III)

Base Information

• Chemical Name: (Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III)
• CAS No.: 34387-57-0
• Molecular Formula: C₃₈H₃₃Cl₃NP₂Re
• Molecular Weight: 858.2
• DSSTox Substance ID: DTXSID40578819
• Mol file: 34387-57-0.mol

Synonyms:34387-57-0;(Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III);acetonitrile;trichlororhenium;triphenylphosphane;(Acetonitrile)trichlorobis(triphenyl-;DTXSID40578819;(Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III), 97%

Chemical Property of (Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III)

Chemical Property:

• Melting Point: 210 °C (dec.)(lit.)
• PSA: 50.97000
• LogP: -1.56852
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 857.071134
• Heavy Atom Count: 45
• Complexity: 239

Purity/Quality:

99%min ^*data from raw suppliers

(Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III) 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC#N.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Re](Cl)Cl
• Uses: Catalyst for addition of tetrahalomethanes to alkenes and 1-omega-dienesReactant for synthesis of:Re(III) complexes containing 2-benzoylpyridineRhenium(IV) and (V) complexesRhenium triphosphorus macrocycle complexes and reactions with alkenesReactant for rhenium chemistry of azooximes

Technology Process of (Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III)

There total 2 articles about (Acetonitrile)trichlorobis(triphenylphosphine)rhenium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

trichlorooxobis(triphenylphosphine)rhenium(V) (34248-12-9) + N,N-Bis(trimethylsilyl)aminodiphenylphosphan (13685-61-5) + triphenylphosphine (603-35-0) + acetonitrile (75-05-8,26809-02-9) → [ReCl2(MeCN)(PPh3)2(N=C(CH3)P(O)Ph2] (849371-27-3) + acetonitrile(trichloro)bis(triphenylphosphine)-rhenium(III) (16009-56-6,34387-57-0)

Guidance literature:

In acetonitrile; under N2; a mixt. of Re-contg. compd. (1.20 mmol), Si-contg. compd. (1.20 mmol), and PPh3 (2.64 mmol) in MeCN was heated under reflux for 2 h; the soln. was filtered hot; the complex was washed with MeCN and dried under vac.; the filtrate was left to cool and after 24 h a mixt. of greenand orange crystals was formed;

DOI:10.1039/b417068g

Reference yield:

[ReOCl3(PPh3)2] + triphenylphosphine (603-35-0) + acetonitrile (75-05-8,26809-02-9) → (OC-6-13)-(acetonitrile-N)trichloro-bis(triphenylphosphine-P)rhenium(III) (16009-56-6,34387-57-0)

Guidance literature:

In toluene; (Ar); refluxing (2 h); pptn. (ethanol), purifn. by recrystn. (CH2Cl2/ethanol);

DOI:10.1016/0020-1693(95)04657-U

Reference yield: 92.0%

acetonitrile(trichloro)bis(triphenylphosphine)-rhenium(III) (16009-56-6,34387-57-0) + bis-diphenylphosphinomethane (2071-20-7) → C43H37Cl3P3Re

Guidance literature:

In toluene; for 2h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1021/acs.organomet.0c00049

upstream raw materials:

triphenylphosphine

acetonitrile

trichlorooxobis(triphenylphosphine)rhenium(V)

N,N-Bis(trimethylsilyl)aminodiphenylphosphan

Downstream raw materials:

C₄₀H₃₃Cl₂N₂P₂ReS

mer-{ReCl₃(PPh₃)2(t-BuCN)}

mer-{ReCl₃(PPh₃)2(CH₃COOCH₂CN)}

trans-[ReCl₃(CN(CH₂)2-N-morpholinyl)(triphenylphosphane)2]

Refernces

• 1、 Pearson, Celine,Beauchamp, Andre L.. "(1)H NMR study of monomeric chloro-rhenium(III) complexes with triarylphosphines and nitriles". . p. 13 - 18. Retrieved 2008/10/08.