(4R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-cyclohex-1-enecarboxylic acid methyl ester

Base Information

Chemical Name:(4R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-cyclohex-1-enecarboxylic acid methyl ester
CAS No.:173914-20-0
Molecular Formula:C₁₄H₂₆O₄Si
Molecular Weight:286.444
Hs Code.:

Synonyms:(4R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-cyclohex-1-enecarboxylic acid methyl ester

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Chemical Property of (4R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-cyclohex-1-enecarboxylic acid methyl ester

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Technology Process of (4R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-cyclohex-1-enecarboxylic acid methyl ester

There total 4 articles about (4R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-cyclohex-1-enecarboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 173914-19-7
(1S,4S,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-cyclohex-2-ene-1,1-dicarboxylic acid allyl ester methyl ester

: 173914-20-0
(4R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-cyclohex-1-enecarboxylic acid methyl ester

Guidance literature:: With formic acid; palladium diacetate; In 1,4-dioxane; Heating;
DOI:10.1016/S0040-4039(00)78338-9

Reference yield:

: 25991-27-9
methyl 2-oxo-2H-pyrane-3-carboxylate

: 173914-20-0
(4R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-cyclohex-1-enecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / (R)-(+)-1,1'-bi-2-naphthol titanium dichloride diisopropoxide complex / toluene / 24 h / -30 °C

2: 74 percent

3: 86 percent / palladium acetate, formic acid / dioxane / Heating

With formic acid; (R)-(+)-1,1'-bi-2-naphthol titanium dichloride diisopropoxide; palladium diacetate; In 1,4-dioxane; toluene;
DOI:10.1016/S0040-4039(00)78338-9

Reference yield:

: 66031-93-4
tert-butyldimethylsilyl vinyl ether

: 173914-20-0
(4R,6S)-6-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-cyclohex-1-enecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / (R)-(+)-1,1'-bi-2-naphthol titanium dichloride diisopropoxide complex / toluene / 24 h / -30 °C

2: 74 percent

3: 86 percent / palladium acetate, formic acid / dioxane / Heating

With formic acid; (R)-(+)-1,1'-bi-2-naphthol titanium dichloride diisopropoxide; palladium diacetate; In 1,4-dioxane; toluene;
DOI:10.1016/S0040-4039(00)78338-9