Sodium; (Z)-7-[(1S,2R,3R,4R)-3-(4-dimethylamino-benzenesulfonylamino)-bicyclo[2.2.1]hept-2-yl]-hept-5-enoate

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Chemical Name:Sodium; (Z)-7-[(1S,2R,3R,4R)-3-(4-dimethylamino-benzenesulfonylamino)-bicyclo[2.2.1]hept-2-yl]-hept-5-enoate
CAS No.:115303-24-7
Molecular Formula:C₂₂H₃₁N₂O₄S*Na
Molecular Weight:442.555
Hs Code.:

Synonyms:Sodium; (Z)-7-[(1S,2R,3R,4R)-3-(4-dimethylamino-benzenesulfonylamino)-bicyclo[2.2.1]hept-2-yl]-hept-5-enoate

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Chemical Property of Sodium; (Z)-7-[(1S,2R,3R,4R)-3-(4-dimethylamino-benzenesulfonylamino)-bicyclo[2.2.1]hept-2-yl]-hept-5-enoate

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Technology Process of Sodium; (Z)-7-[(1S,2R,3R,4R)-3-(4-dimethylamino-benzenesulfonylamino)-bicyclo[2.2.1]hept-2-yl]-hept-5-enoate

There total 12 articles about Sodium; (Z)-7-[(1S,2R,3R,4R)-3-(4-dimethylamino-benzenesulfonylamino)-bicyclo[2.2.1]hept-2-yl]-hept-5-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 115267-06-6
(Z)-7-[(1S,2R,3R,4R)-3-(4-Dimethylamino-benzenesulfonylamino)-bicyclo[2.2.1]hept-2-yl]-hept-5-enoic acid

: 115303-24-7
Sodium; (Z)-7-[(1S,2R,3R,4R)-3-(4-dimethylamino-benzenesulfonylamino)-bicyclo[2.2.1]hept-2-yl]-hept-5-enoate

Guidance literature:: With sodium methylate; In methanol;
DOI:10.1021/jm00117a028

Reference yield:

: 17814-85-6
(4-carboxybutyl)triphenylphosphonium bromide

: 115303-24-7
Sodium; (Z)-7-[(1S,2R,3R,4R)-3-(4-dimethylamino-benzenesulfonylamino)-bicyclo[2.2.1]hept-2-yl]-hept-5-enoate

Guidance literature:: Multi-step reaction with 6 steps

1: dimsylsodium / dimethylsulfoxide / 4 h / 25 °C

2: 2.8 g / diethyl ether

3: 99.6 percent / various solvent(s) / 3 h / 45 °C

4: 33 percent / triethylamine / CH₂Cl₂

5: 1 N KOH / methanol / 6 h / 23 °C

6: 90 percent / sodium methoxide / methanol

With potassium hydroxide; dimsylsodium; sodium methylate; triethylamine; In methanol; diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jm00117a028

Reference yield:

: 75040-20-9
exo-3-allylnorcamphor

: 115303-24-7
Sodium; (Z)-7-[(1S,2R,3R,4R)-3-(4-dimethylamino-benzenesulfonylamino)-bicyclo[2.2.1]hept-2-yl]-hept-5-enoate

Guidance literature:: Multi-step reaction with 11 steps

1: hydroxylamine hydrochloride, KOH / methanol / 0.5 h / 0 °C

2: 78.4 percent / LiAlH₄ / tetrahydrofuran / 4 h / Heating

3: 1.97 g / pyridine / CH₂Cl₂ / 0.5 h / 0 °C

4: 100 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 3 h / 20 °C

5: HIO₄ / dioxane; H₂O / 4 h / 25 °C

6: dimsylsodium / dimethylsulfoxide / 4 h / 25 °C

7: 2.8 g / diethyl ether

8: 99.6 percent / various solvent(s) / 3 h / 45 °C

9: 33 percent / triethylamine / CH₂Cl₂

10: 1 N KOH / methanol / 6 h / 23 °C

11: 90 percent / sodium methoxide / methanol

With pyridine; potassium hydroxide; lithium aluminium tetrahydride; dimsylsodium; hydroxylamine hydrochloride; sodium methylate; periodic acid; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; 1,4-dioxane; methanol; diethyl ether; dichloromethane; water; dimethyl sulfoxide;
DOI:10.1021/jm00117a028