neopentyloxy(diphenyl)-λ⁶-sulfanenitrile

Base Information

• Chemical Name: neopentyloxy(diphenyl)-λ⁶-sulfanenitrile
• CAS No.: 212077-64-0
• Molecular Formula: C₁₇H₂₁NOS
• Molecular Weight: 287.426
• Mol file: 212077-64-0.mol

Synonyms:neopentyloxy(diphenyl)-λ⁶-sulfanenitrile

Chemical Property of neopentyloxy(diphenyl)-λ⁶-sulfanenitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of neopentyloxy(diphenyl)-λ⁶-sulfanenitrile

There total 2 articles about neopentyloxy(diphenyl)-λ⁶-sulfanenitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

fluoro(diphenyl)-λ6-sulfanenitrile (67248-39-9) + sodium tert-pentoxide (3561-85-1) → neopentyloxy(diphenyl)-λ6-sulfanenitrile (212077-64-0)

Guidance literature:

In dimethyl sulfoxide; at 20 ℃; for 0.166667h;

DOI:10.1246/bcsj.71.1629

Reference yield:

S,S-Diphenyl-N.bromosulfilimine (42787-34-8) → neopentyloxy(diphenyl)-λ6-sulfanenitrile (212077-64-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 65 percent / tetrabutylammonium fluoride / tetrahydrofuran / 3 h / 0 °C

2: 61 percent / dimethylsulfoxide / 0.17 h / 20 °C

With tetrabutyl ammonium fluoride; In tetrahydrofuran; dimethyl sulfoxide; 1: Substitution / 2: Substitution;

DOI:10.1246/bcsj.71.1629

Reference yield: 99.0%

neopentyloxy(diphenyl)-λ6-sulfanenitrile (212077-64-0) → tert-amyl alcohol-d1 (4712-41-8) + S,S-diphenylsulphoximine (22731-83-5)

Guidance literature:

With [D₃]acetonitrile; water-d2; In phosphate buffer; at 20 ℃; for 0.75h; pH=6.1; Further Variations:; pH-values; Reagents; Solvents; Temperatures; Kinetics; Thermodynamic data; Product distribution;

DOI:10.1246/bcsj.73.957

upstream raw materials:

fluoro(diphenyl)-λ⁶-sulfanenitrile

sodium tert-pentoxide

S,S-Diphenyl-N_.bromosulfilimine

Downstream raw materials:

tert-amyl alcohol-d₁

S,S-diphenylsulphoximine

2-methyl-but-2-ene

neopentyl tosylate