[3,5-Bis-(3,5-bis-phenylsulfanylmethyl-phenoxymethyl)-phenyl]-acetonitrile

Base Information

Chemical Name:[3,5-Bis-(3,5-bis-phenylsulfanylmethyl-phenoxymethyl)-phenyl]-acetonitrile
CAS No.:168414-91-3
Molecular Formula:C₅₀H₄₃NO₂S₄
Molecular Weight:818.161
Hs Code.:

Synonyms:[3,5-Bis-(3,5-bis-phenylsulfanylmethyl-phenoxymethyl)-phenyl]-acetonitrile

Suppliers and Price of [3,5-Bis-(3,5-bis-phenylsulfanylmethyl-phenoxymethyl)-phenyl]-acetonitrile

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [3,5-Bis-(3,5-bis-phenylsulfanylmethyl-phenoxymethyl)-phenyl]-acetonitrile

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

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Technology Process of [3,5-Bis-(3,5-bis-phenylsulfanylmethyl-phenoxymethyl)-phenyl]-acetonitrile

There total 8 articles about [3,5-Bis-(3,5-bis-phenylsulfanylmethyl-phenoxymethyl)-phenyl]-acetonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 168414-97-9
α,α'-dibromo-α''-cyanomesitylene

: 168414-96-8
3,5-bis[(phenylsulfanyl)methyl]phenol

: 168414-91-3
[3,5-Bis-(3,5-bis-phenylsulfanylmethyl-phenoxymethyl)-phenyl]-acetonitrile

Guidance literature:: With potassium carbonate; In acetonitrile;
DOI:10.1021/ja00136a037

Reference yield:

: 13036-02-7
Dimethyl 5-hydroxyisophthalate

: 168414-91-3
[3,5-Bis-(3,5-bis-phenylsulfanylmethyl-phenoxymethyl)-phenyl]-acetonitrile

Guidance literature:: Multi-step reaction with 6 steps

1: 89 percent / Et₃N, DMAP / CH₂Cl₂ / Ambient temperature

2: 93 percent / LiAlH₄ / tetrahydrofuran / Ambient temperature

3: 92 percent / MsCl, Et₃N / CHCl₃ / 0 - 50 °C

4: 1.) NaH / 1.) THF, 1h, 2.) THF, 50 deg C, overnight

5: CsF / tetrahydrofuran / 50 °C

6: 1.) K₂CO₃ / 1.) MeCN, RT, 1 h, 2.) MeCN, RT, 4 d

With dmap; lithium aluminium tetrahydride; sodium hydride; potassium carbonate; methanesulfonyl chloride; triethylamine; cesium fluoride; In tetrahydrofuran; dichloromethane; chloroform;
DOI:10.1039/a608577f

Reference yield:

: 108-98-5
thiophenol

: 168414-91-3
[3,5-Bis-(3,5-bis-phenylsulfanylmethyl-phenoxymethyl)-phenyl]-acetonitrile

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) TBDMSiCl

2: K₂CO₃ / acetonitrile

With potassium carbonate; tert-butyldimethylsilyl chloride; In acetonitrile;
DOI:10.1021/ja00136a037