[(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF₄

Base Information

Chemical Name:[(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF₄
CAS No.:881913-67-3
Molecular Formula:BF₄*C₂₅H₁₇N₃O₄PRh₂
Molecular Weight:747.017
Hs Code.:

[(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF<sub>4</sub>

Synonyms:[(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF₄

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Chemical Property of [(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF₄

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Technology Process of [(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF₄

There total 1 articles about [(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 881493-89-6
[(cod)Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(cod)]BF₄

: 201230-82-2
carbon monoxide

: 881913-67-3
[(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF₄

Guidance literature:: In dichloromethane; soln. Rh-Rh complex in CH2Cl2 was stirred under CO atm. (1 atm.) for 3 hat room temp.; hexane was added, ppt. was washed with ether and dried in vacuo; elem. anal.;
DOI:10.1021/om050897e

Reference yield: 63.0%

: 881913-67-3
[(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF₄

: 766-97-2
4-n-methylphenylacetylene

: (CO)Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)(μ-CC-p-tol)*CH2Cl2

Guidance literature:: With n-BuLi; In tetrahydrofuran; under inert atm. to soln. HCC-p-tol in THF at -75°C n-BuLi was added, after 10 min soln. Rh-Rh complex in THF was added and stirred for 10 min at -75°C, for 30 min at 0°C, and for 1 h at room temp.; soln. was filtered through alumina and concd. in vacuo, Et2O was added (workup at 0°C); elem. anal.;
DOI:10.1021/om050897e

Reference yield: 46.0%

: 881913-67-3
[(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF₄

: 1066-54-2
trimethylsilylacetylene

: 881913-87-7
(CO)Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)(μ-CCSiMe3)

Guidance literature:: With n-BuLi; In tetrahydrofuran; under inert atm. to soln. HCCSiMe3 in THF at -75°C n-BuLi was added, after 10 min soln. Rh-Rh complex in THF was added and stirred for 10min at -75°C, for 30 min at 0°C, and for 1 h at room temp .; soln. was filtered through alumina and concd. in vacuo, Et2O was added;
DOI:10.1021/om050897e