buta-2,3-dien-1-yl 4-methylbenzenesulfonate

Base Information

• Chemical Name: buta-2,3-dien-1-yl 4-methylbenzenesulfonate
• CAS No.: 147396-58-5
• Molecular Formula: C₁₁H₁₂O₃S
• Molecular Weight: 224.28
• Mol file: 147396-58-5.mol

Synonyms:buta-2,3-dien-1-yl 4-methylbenzenesulfonate

Chemical Property of buta-2,3-dien-1-yl 4-methylbenzenesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of buta-2,3-dien-1-yl 4-methylbenzenesulfonate

There total 1 articles about buta-2,3-dien-1-yl 4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2,3-butadien-1-ol (18913-31-0) + p-toluenesulfonyl chloride (98-59-9) → buta-2,3-dien-1-yl 4-methylbenzenesulfonate (147396-58-5)

Guidance literature:

With potassium hydroxide; In diethyl ether; for 0.75h;

DOI:10.1021/ja00094a037

Reference yield: 99.0%

N-benzhydryl-2-cyclopropylideneethanamine (949569-81-7) + buta-2,3-dien-1-yl 4-methylbenzenesulfonate (147396-58-5) → N-benzhydryl-N-(2-cyclopropylideneethyl)buta-2,3-dien-1-amine (949569-68-0)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 24h;

DOI:10.1002/adsc.200600347

Reference yield: 81.0%

benzaldehyde (100-52-7) + buta-2,3-dien-1-yl 4-methylbenzenesulfonate (147396-58-5) → (S)-2-methylene-1-phenylbut-3-en-1-ol

Guidance literature:

buta-2,3-dien-1-yl 4-methylbenzenesulfonate; With tri-n-butyltin lithium; In tetrahydrofuran; at -78 ℃; for 1h;

benzaldehyde; With titanium(IV) isopropylate; (i-C₃H₇)SB(C₂H₅)2; (S)-[1,1']-binaphthalenyl-2,2'-diol; at -20 ℃; for 8h;

DOI:10.1039/a908119d

upstream raw materials:

2,3-butadien-1-ol

p-toluenesulfonyl chloride

Downstream raw materials:

(R)-2-methylene-1-o-tolylbut-3-en-1-ol

methyl (R)-(-)-4-methylcyclohex-3-ene-4-carboxylate

methyl (S)-(+)-4-methylcyclohex-1-ene-4-carboxylate

N-benzhydryl-N-(2-cyclopropylideneethyl)buta-2,3-dien-1-amine