[Os(CMe)(PCy₃)2Cl₃]

Base Information

Chemical Name:[Os(CMe)(PCy₃)2Cl₃]
CAS No.:952649-03-5
Molecular Formula:C₃₈H₆₉Cl₃OsP₂
Molecular Weight:884.472
Hs Code.:

[Os(CMe)(PCy<sub>3</sub>)2Cl<sub>3</sub>]

Synonyms:[Os(CMe)(PCy₃)2Cl₃]

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Chemical Property of [Os(CMe)(PCy₃)2Cl₃]

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Technology Process of [Os(CMe)(PCy₃)2Cl₃]

There total 1 articles about [Os(CMe)(PCy₃)2Cl₃] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.1%

: 353750-38-6
Os(CMe)(PPh₃)2Cl₃

: 2622-14-2
tricyclohexylphosphine

: 952649-03-5
[Os(CMe)(PCy₃)2Cl₃]

Guidance literature:: In tetrahydrofuran; under N2 atm. to suspn. Os complex in THF PCy3 was added and refluxed for 1.2 h; react. mixt. was cooled to room temp., solvent was removed in vacuo, residue was slurried in pentane an Et2O, stirred for 10 min and filtered, ppt. was washed with pentane and Et2O, dissolved in CH2Cl2 and kept at -35°C overnight; elem. anal.;
DOI:10.1021/om070208u

Reference yield: 67.0%

: 952649-03-5
[Os(CMe)(PCy₃)2Cl₃]

: 2923-28-6
silver trifluoromethanesulfonate

: 952649-02-4
[Os(CMe)(PCy₃)2Cl₂][OTf]

Guidance literature:: In dichloromethane; under N2 atm. to soln. Os complex in CH2Cl2 AgOTf was added and stirred for 30 min; soln. was filtered through Celite and evapd. in vacuo, residue was suspended in Et2O, stirred for 5 min, filtered, washed with Et2O and dried invacuo; elem. anal.;
DOI:10.1021/om070208u

Reference yield: 58.9%

: 952649-03-5
[Os(CMe)(PCy₃)2Cl₃]

: 952649-04-6
[Os(=CCH₂)(PCy₃)2Cl₂]

Guidance literature:: With lithium tert-butoxide; In tetrahydrofuran; under N2 atm. to Os complex in THF t-BuOLi in THF was added and stirred at 30°C for 30 min; soln. was filtered and evapd., residue was triturated with pentane, dissolved in CH2Cl2, layered with Et2O and kept at -35°C overnight, ppt. was filtered, washed with cold CH2Cl2 and dried in vacuo; elem. anal.;
DOI:10.1021/om070208u