IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2BF₄

Base Information

• Chemical Name: IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2BF₄
• CAS No.: 470664-03-0
• Molecular Formula: BF₄*C₄₉H₄₂IrOP₂
• Molecular Weight: 987.844
• Mol file: 470664-03-0.mol

Synonyms:IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2BF₄

Chemical Property of IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2BF₄

There total 1 articles about IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-)=IrC₆H₅C₆H₇(CO)(P(C₆H₅)3)2BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

tetrafluoroboric acid + Ir(CCC6H5)(CHCH2)2(CO)(P(C6H5)3)2 (470663-84-4) → IrC6H5C6H7(CO)(P(C6H5)3)2(1+)*BF4(1-)=IrC6H5C6H7(CO)(P(C6H5)3)2BF4 (470664-03-0)

Guidance literature:

In diethyl ether; chloroform; mixt. of Ir-complex and HBF4 (in Et2O) in CHCl3 was stirred for 1 h at 25°C; Et2O was added, filtered, washed with n-pentane, dried under vac.; elem.anal.;

DOI:10.1021/om020410r

Reference yield:

IrC6H5C6H7(CO)(P(C6H5)3)2(1+)*BF4(1-)=IrC6H5C6H7(CO)(P(C6H5)3)2BF4 (470664-03-0) + tetraethylammonium chloride (56-34-8) → bis(triphenylphosphine)carbonyliridium(I) chloride (59246-46-7,14871-41-1,15318-31-7)

Guidance literature:

In chloroform; byproducts: C6H5-HEX; soln. of Ir-complex and ligand in CHCl3 was stirred at 25°C for 1h under N2; extd. with H2O, n-pentane was added, filtered;

DOI:10.1021/om020410r

Reference yield:

IrC6H5C6H7(CO)(P(C6H5)3)2(1+)*BF4(1-)=IrC6H5C6H7(CO)(P(C6H5)3)2BF4 (470664-03-0) + acetonitrile (75-05-8,26809-02-9) → Ir(CH3CN)(CO)(P(C6H5)3)2

Guidance literature:

In chloroform; byproducts: C6H5-HEX; soln. of Ir-complex and ligand in CHCl3 was stirred at 25°C for 1h under N2; extd. with H2O, n-pentane was added, filtered;

DOI:10.1021/om020410r

upstream raw materials:

Ir(CCC₆H₅)(CHCH₂)2(CO)(P(C₆H₅)3)2

Downstream raw materials:

bis(triphenylphosphine)carbonyliridium(I) chloride