phenyl-9-o-carboranyliodonium tetrafluoroborate

Base Information

Chemical Name:phenyl-9-o-carboranyliodonium tetrafluoroborate
CAS No.:81353-28-8
Molecular Formula:BF₄*C₈H₁₆B₁₀I
Molecular Weight:434.034
Hs Code.:

Synonyms:phenyl-9-o-carboranyliodonium tetrafluoroborate

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Chemical Property of phenyl-9-o-carboranyliodonium tetrafluoroborate

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of phenyl-9-o-carboranyliodonium tetrafluoroborate

There total 1 articles about phenyl-9-o-carboranyliodonium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 13826-83-0
ammonium tetrafluroborate

: 9-iodo-o-carborane bistrifluoroacetate

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: 81353-28-8
phenyl-9-o-carboranyliodonium tetrafluoroborate

Guidance literature:: In sulfuric acid; acetic acid; The reaction mixture was cooled to 0 °C with intense stirring, stirred at 20 °C until the oxidizing agent was depleted, poured into 200 g of ice. The soln. of iodonium salt was washed with benzene, saturated with NH4BF4.; Extraction by a CH3NO2-CHCl3 mixture. The organic extracts were evaporated in a vacuum at 35-40 °C, the carborane was precipitated from the residue by adding an excess of ether. Reprecipitation from acetone and from CH3NO2 by ether. Elem. anal.;

Reference yield: 100.0%

: 81353-28-8
phenyl-9-o-carboranyliodonium tetrafluoroborate

: 7681-82-5,24359-64-6,41927-88-2,115813-40-6
sodium iodide

: 81353-29-9
phenyl-9-0-carboranyliodonium iodide

Guidance literature:: In water; acetone; The precipitated iodide was washed with water and ether and dried in the dark. Elem. anal.;

Reference yield: 76.0%

: 81353-28-8
phenyl-9-o-carboranyliodonium tetrafluoroborate

: 92-52-4,1594-86-1
biphenyl

: 17830-03-4
9-iodo-o-carborane

: 426-79-9
tetraphenylphosphonium tetrafluoroborate

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

Guidance literature:: With triphenylphosphine; In acetone; Irradiation (UV/VIS); a soln. of fluoroborate salt and P(C6H5)3 illuminated for 7.5 h; chromy.; treated with ether; reprecipitated from acetone soln. with ether; filtrated treated with CH3I; filtered; evapd.; extracted with hot hexane; sublimed;
DOI:10.1007/BF00957970