9-Iodo-o-carborane

Base Information

Chemical Name:9-Iodo-o-carborane
CAS No.:17830-03-4
Molecular Formula:C2H11 B10 I
Molecular Weight:270.124
Hs Code.:

Synonyms:9-Iodo-1,2-dicarbadodecaborane(12);9-Iodo-closo-1,2-dicarbadodecaborane(12); 9-Iodo-o-carborane

Suppliers and Price of 9-Iodo-o-carborane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
9-Iodo-o-carborane
25mg
$ 55.00

Total 3 raw suppliers

Chemical Property of 9-Iodo-o-carborane

Chemical Property:

PSA：0.00000
LogP:-4.92300

Purity/Quality:

99% ^*data from raw suppliers

9-Iodo-o-carborane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses 9-Iodo-o-carborane is a versatile reactant used in Pd-catalyzed coupling reactions of amides with iodo- and diiodocarborane to give aminocarboranes and diamidocarborane. It is also used as a reactant in the carborane-enhanced two-photon absorption of tribranched fluorophores for fluorescence microscopy imaging.

Technology Process of 9-Iodo-o-carborane

There total 6 articles about 9-Iodo-o-carborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 16872-09-6
1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 17830-03-4
9-iodo-o-carborane

: 17702-35-1
9,12-diiodo-1,2-dicarba-closo-dodecarborane⁽¹²⁾

Guidance literature:: In neat (no solvent); (under N2); tube charged with B-compound and I2 under vac., cooled to liq. N2 temp., sealed, heated to 120°C for 30 min, maintained for 2.5 h, slowly cooled to room temp.; sublimed at 50°C under reduced pressure;
DOI:10.1021/ic800362z

Reference yield: 82.0%

: 16872-09-6
1,2-dicarba-closo-dodecaborane⁽¹²⁾

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 29386-25-2
8,9-diiodo-1,2-dicarba-closo-dodecarborane⁽¹²⁾

: 17830-03-4
9-iodo-o-carborane

: 17702-35-1
9,12-diiodo-1,2-dicarba-closo-dodecarborane⁽¹²⁾

: 20313-41-1
8,9,12-triiiodo-1,2-dicarba-closo-dodecaborane

Guidance literature:: In neat (no solvent); (under N2); tube charged with B-compound and I2 under vac., cooled to liq. N2 temp., sealed, heated to 170°C for 30 min, maintained for 3.5 h, slowly cooled to room temp.; sublimed at 50°C under reduced pressure, recrystd. from hexane/CHCl3 6:1;
DOI:10.1021/ic800362z

Reference yield: 76.0%

: 81353-28-8
phenyl-9-o-carboranyliodonium tetrafluoroborate

: 92-52-4,1594-86-1
biphenyl

: 17830-03-4
9-iodo-o-carborane

: 426-79-9
tetraphenylphosphonium tetrafluoroborate

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

Guidance literature:: With triphenylphosphine; In acetone; Irradiation (UV/VIS); a soln. of fluoroborate salt and P(C6H5)3 illuminated for 7.5 h; chromy.; treated with ether; reprecipitated from acetone soln. with ether; filtrated treated with CH3I; filtered; evapd.; extracted with hot hexane; sublimed;
DOI:10.1007/BF00957970