N,N'-[(1Z,4Z)-1-cyclopropyl-3-oxoundeca-1,4-diene-2,4-diyl]bis(N-methyltosylamide)

Base Information

Chemical Name:N,N'-[(1Z,4Z)-1-cyclopropyl-3-oxoundeca-1,4-diene-2,4-diyl]bis(N-methyltosylamide)
CAS No.:1486515-82-5
Molecular Formula:C₃₀H₄₀N₂O₅S₂
Molecular Weight:572.79
Hs Code.:

Synonyms:N,N'-[(1Z,4Z)-1-cyclopropyl-3-oxoundeca-1,4-diene-2,4-diyl]bis(N-methyltosylamide)

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Chemical Property of N,N'-[(1Z,4Z)-1-cyclopropyl-3-oxoundeca-1,4-diene-2,4-diyl]bis(N-methyltosylamide)

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Technology Process of N,N'-[(1Z,4Z)-1-cyclopropyl-3-oxoundeca-1,4-diene-2,4-diyl]bis(N-methyltosylamide)

There total 9 articles about N,N'-[(1Z,4Z)-1-cyclopropyl-3-oxoundeca-1,4-diene-2,4-diyl]bis(N-methyltosylamide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 201230-82-2
carbon monoxide

: 1486515-50-7
(E)-N-methyl-N-(1-tributylstannyl-oct-1-en-1-yl)tosylamide

: 1486515-55-2
(E)-N-(2-cyclopropyl-1-iodo-vinyl)-N-methyltosylamide

: 1486515-82-5
N,N'-[(1Z,4Z)-1-cyclopropyl-3-oxoundeca-1,4-diene-2,4-diyl]bis(N-methyltosylamide)

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) chloride; In dimethyl sulfoxide; at 55 ℃; for 16h; Schlenk technique;
DOI:10.1021/ol4031028

Reference yield:

: 640-61-9
N-methyl-p-toluenesulfonylamide

: 1486515-82-5
N,N'-[(1Z,4Z)-1-cyclopropyl-3-oxoundeca-1,4-diene-2,4-diyl]bis(N-methyltosylamide)

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate; copper(II) sulfate; 1,10-Phenanthroline / toluene; water / 80 °C

2: hydroquinone; tris(t-butyl isocyanide)tricarbonylmolybdenum(O); carbon monoxide / tetrahydrofuran / 55 °C / Schlenk technique

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) chloride / dimethyl sulfoxide / 16 h / 55 °C / Schlenk technique

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; 1,10-Phenanthroline; tris(t-butyl isocyanide)tricarbonylmolybdenum(O); carbon monoxide; potassium carbonate; copper(II) sulfate; hydroquinone; copper(l) chloride; In tetrahydrofuran; water; dimethyl sulfoxide; toluene; 3: |Stille Cross Coupling;
DOI:10.1021/ol4031028

Reference yield:

: 1263053-70-8
N-(cyclopropylethynyl)-N,4-dimethylbenzenesulfonamide

: 1486515-82-5
N,N'-[(1Z,4Z)-1-cyclopropyl-3-oxoundeca-1,4-diene-2,4-diyl]bis(N-methyltosylamide)

Guidance literature:: Multi-step reaction with 3 steps

1: hydroquinone; tris(t-butyl isocyanide)tricarbonylmolybdenum(O); carbon monoxide / tetrahydrofuran / 55 °C / Schlenk technique

2: iodine / dichloromethane / 3 h / 0 °C

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) chloride / dimethyl sulfoxide / 16 h / 55 °C / Schlenk technique

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tris(t-butyl isocyanide)tricarbonylmolybdenum(O); carbon monoxide; iodine; hydroquinone; copper(l) chloride; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; 3: |Stille Cross Coupling;
DOI:10.1021/ol4031028