C₂₄H₁₈N⁽¹⁵⁾N

Base Information

• Chemical Name: C₂₄H₁₈N⁽¹⁵⁾N
• CAS No.: 1612775-03-7
• Molecular Formula: C₂₄H₁₈N₂
• Molecular Weight: 335.414
• Mol file: 1612775-03-7.mol

Synonyms:C₂₄H₁₈N⁽¹⁵⁾N

Chemical Property of C₂₄H₁₈N⁽¹⁵⁾N

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₄H₁₈N⁽¹⁵⁾N

There total 3 articles about C₂₄H₁₈N⁽¹⁵⁾N which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

diphenylamine (122-39-4) + 15N-9H-carbazole → C24H18N(15)N (1612775-03-7)

Guidance literature:

With Isopropylbenzene; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; oxygen; copper diacetate; In 1,1,2,2-tetrachloroethylene; acetic acid; at 150 ℃; for 24h;

DOI:10.1002/anie.201308601

Reference yield:

(15N)-aniline (7022-92-6) → C24H18N(15)N (1612775-03-7)

Guidance literature:

Multi-step reaction with 4 steps

1.1: triethylamine / dichloromethane / 20 °C

2.1: copper(l) iodide; 2,2,6,6-tetramethylheptane-3,5-dione; potassium phosphate / toluene / 24 h / 140 °C / Schlenk technique; Inert atmosphere

3.1: palladium diacetate; silver(l) oxide / acetic acid / 36 h / 140 °C / Schlenk technique; Inert atmosphere

3.2: Heating

4.1: Isopropylbenzene; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper diacetate; oxygen / acetic acid; 1,1,2,2-tetrachloroethylene / 24 h / 150 °C

With potassium phosphate; copper(l) iodide; Isopropylbenzene; 2,2,6,6-tetramethylheptane-3,5-dione; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; oxygen; copper diacetate; palladium diacetate; triethylamine; silver(l) oxide; In 1,1,2,2-tetrachloroethylene; dichloromethane; acetic acid; toluene;

DOI:10.1002/anie.201308601

Reference yield:

acetanilide-15N (1449-75-8) → C24H18N(15)N (1612775-03-7)

Guidance literature:

Multi-step reaction with 3 steps

1.1: copper(l) iodide; 2,2,6,6-tetramethylheptane-3,5-dione; potassium phosphate / toluene / 24 h / 140 °C / Schlenk technique; Inert atmosphere

2.1: palladium diacetate; silver(l) oxide / acetic acid / 36 h / 140 °C / Schlenk technique; Inert atmosphere

2.2: Heating

3.1: Isopropylbenzene; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper diacetate; oxygen / acetic acid; 1,1,2,2-tetrachloroethylene / 24 h / 150 °C

With potassium phosphate; copper(l) iodide; Isopropylbenzene; 2,2,6,6-tetramethylheptane-3,5-dione; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; oxygen; copper diacetate; palladium diacetate; silver(l) oxide; In 1,1,2,2-tetrachloroethylene; acetic acid; toluene;

DOI:10.1002/anie.201308601

upstream raw materials:

(15N)-aniline

acetanilide-¹⁵N

diphenylamine