(HC[(CMe)(N-2,6-iPr₂C₆H₃)]2)AlClI

Base Information

• Chemical Name: (HC[(CMe)(N-2,6-iPr₂C₆H₃)]2)AlClI
• CAS No.: 844867-44-3
• Molecular Formula: C₂₉H₄₁AlClIN₂
• Molecular Weight: 606.997
• Mol file: 844867-44-3.mol

Synonyms:(HC[(CMe)(N-2,6-iPr₂C₆H₃)]2)AlClI

Chemical Property of (HC[(CMe)(N-2,6-iPr₂C₆H₃)]2)AlClI

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (HC[(CMe)(N-2,6-iPr₂C₆H₃)]2)AlClI

There total 1 articles about (HC[(CMe)(N-2,6-iPr₂C₆H₃)]2)AlClI which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

(HC[(CMe)(N-2,6-iPr2C6H3)]2)AlClMe + iodine (7553-56-2,12190-71-5,8031-47-8) → (HC[(CMe)(N-2,6-iPr2C6H3)]2)AlClI (844867-44-3)

Guidance literature:

In toluene; under N2 atm. toluene soln. Al complexand I2 was stirred for 5 days; soln. was concd. and kept at 4°C for 24 h; elem. anal.;

DOI:10.1021/om049339a

Reference yield: 77.0%

lithium aluminium tetrahydride (16853-85-3) + (HC[(CMe)(N-2,6-iPr2C6H3)]2)AlClI (844867-44-3) → C29H42AlClN2

Guidance literature:

In diethyl ether; at -78 - 20 ℃; for 1.5h; Inert atmosphere;

DOI:10.1002/chem.201802603

Reference yield: 70.0%

(HC[(CMe)(N-2,6-iPr2C6H3)]2)AlClI (844867-44-3) + water (7732-18-5) → [(HC[(CMe)(N-2,6-iPr2C6H3)]2)AlCl(μ-OH)]2

Guidance literature:

With 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene; In toluene; under N2 atm. to mixt. Al complex and (CN(iPr)C2Me2N(iPr)) in toluene at0°C H2O was added (1:1:1), allowed to warm to room temp. and sti rred for 12 h; soln. was filtered and dried in vacuo, residue was extd. with n-hexane and kept at 4°C; elem. anal.;

DOI:10.1021/om049339a

upstream raw materials:

iodine

Downstream raw materials:

(HC[(CMe)(N-2,6-iPr₂C₆H₃)]2)Al(OH)2