Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundeca-2,4-dienoate

Base Information

Chemical Name:Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundeca-2,4-dienoate
CAS No.:247166-82-1
Molecular Formula:C₃₁H₃₈O₅
Molecular Weight:490.64
Hs Code.:

Synonyms:Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundeca-2,4-dienoate

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Chemical Property of Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundeca-2,4-dienoate

Chemical Property:

Purity/Quality:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundeca-2,4-dienoate

There total 17 articles about Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundeca-2,4-dienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 5350-57-2
benzophenone hydrazone

: 29066-42-0
hymeglusin

: 247166-82-1
Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundeca-2,4-dienoate

Guidance literature:: benzophenone hydrazone; With lead(IV) acetate; triethylamine; In dichloromethane; at -20 - 20 ℃;

hymeglusin; In benzene; at 70 ℃; for 1h;

Reference yield: 40.0%

: 247166-81-0
Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundec-2-enoate

: 247166-82-1
Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundeca-2,4-dienoate

Guidance literature:: With samarium diiodide; In tetrahydrofuran; tert-butyl alcohol; for 0.0833333h;

Reference yield:

: 247166-66-1
(2Z,8R)-8-Methylundec-2-en-10-yn-1-ol

: 247166-82-1
Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundeca-2,4-dienoate

Guidance literature:: Multi-step reaction with 9 steps

1.1: Cp₂ZrCl₂ / hexane; 1,2-dichloro-ethane / 40 °C

1.2: 86 percent / I₂ / tetrahydrofuran; hexane; 1,2-dichloro-ethane / 0.5 h / -30 - 0 °C

2.1: 62 percent / PdCl₂(CH₃CN)2 / dimethylformamide / 72 h / 20 °C

3.1: 80 percent / t-BuOOH; Ti(OiPr)4; L-(+)-DIPT / CH₂Cl₂; 2,2,4-trimethyl-pentane / 36 h / -24 °C

4.1: tetra-n-propylammonium perruthenate; NMO; 4 Angstroem molecular sieves / acetonitrile; CH₂Cl₂ / 0.67 h

5.1: KHMDS / toluene; tetrahydrofuran / 2 h

6.1: tetrahydrofuran / 0.75 h

6.2: CAN / acetonitrile / 5 h / 0 - 20 °C

7.1: 57 percent / MCPBA; K₂CO₃ / CH₂Cl₂ / 0.5 h

8.1: O₃ / CH₂Cl₂ / 0.03 h / -78 °C

8.2: 18 percent / NaBH₄/Al₂O₃ / benzene / 14 h / 20 °C

9.1: 40 percent / SmI₂ / tetrahydrofuran; 2-methyl-propan-2-ol / 0.08 h

With titanium(IV) isopropylate; tert.-butylhydroperoxide; N-methyl-2-indolinone; samarium diiodide; tetrapropylammonium perruthennate; zirconocene dichloride; L-(+)-diisopropyl tartrate; 4 A molecular sieve; potassium hexamethylsilazane; potassium carbonate; ozone; 3-chloro-benzenecarboperoxoic acid; dichloro bis(acetonitrile) palladium(II); In tetrahydrofuran; 2,2,4-trimethylpentane; hexane; dichloromethane; 1,2-dichloro-ethane; N,N-dimethyl-formamide; toluene; acetonitrile; tert-butyl alcohol; 1.1: Addition / 1.2: Iodination / 2.1: Stille coupling / 3.1: Epoxidation / 4.1: Oxidation / 5.1: Wittig methylenation / 6.1: Carbonylation / 6.2: Oxidation / 7.1: Epoxidation / 8.1: Oxidation / 8.2: Reduction / 9.1: Elimination;