Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundec-2-enoate

Base Information

Chemical Name:Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundec-2-enoate
CAS No.:247166-81-0
Molecular Formula:C₃₁H₃₈O₆
Molecular Weight:506.639
Hs Code.:

Synonyms:

Suppliers and Price of Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundec-2-enoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundec-2-enoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundec-2-enoate

There total 16 articles about Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundec-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 247166-82-1
Diphenylmethyl [2E,4E,7R,(2'R,3'R)]-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundeca-2,4-dienoate

: 247166-81-0
Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundec-2-enoate

Guidance literature:: With potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 0.0833333h;

Reference yield: 18.0%

: 247166-80-9
Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(4'-oxo-3'-vinyloxetan-2'-yl)-3,5,7-trimethylundec-2-enoate

: 247166-81-0
Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundec-2-enoate

Guidance literature:: Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(4'-oxo-3'-vinyloxetan-2'-yl)-3,5,7-trimethylundec-2-enoate; With ozone; In dichloromethane; at -78 ℃; for 0.025h;

With aluminum oxide; sodium tetrahydroborate; In benzene; at 20 ℃; for 14h;

Reference yield:

: 247166-66-1
(2Z,8R)-8-Methylundec-2-en-10-yn-1-ol

: 247166-81-0
Diphenylmethyl [2E,4R/S,5S/R,7R,(2'R,3'R)]-4,5-epoxy-11-(3'-hydroxymethyl-4'-oxooxetan-2'-yl)-3,5,7-trimethylundec-2-enoate

Guidance literature:: Multi-step reaction with 8 steps

1.1: Cp₂ZrCl₂ / hexane; 1,2-dichloro-ethane / 40 °C

1.2: 86 percent / I₂ / tetrahydrofuran; hexane; 1,2-dichloro-ethane / 0.5 h / -30 - 0 °C

2.1: 62 percent / PdCl₂(CH₃CN)2 / dimethylformamide / 72 h / 20 °C

3.1: 80 percent / t-BuOOH; Ti(OiPr)4; L-(+)-DIPT / CH₂Cl₂; 2,2,4-trimethyl-pentane / 36 h / -24 °C

4.1: tetra-n-propylammonium perruthenate; NMO; 4 Angstroem molecular sieves / acetonitrile; CH₂Cl₂ / 0.67 h

5.1: KHMDS / toluene; tetrahydrofuran / 2 h

6.1: tetrahydrofuran / 0.75 h

6.2: CAN / acetonitrile / 5 h / 0 - 20 °C

7.1: 57 percent / MCPBA; K₂CO₃ / CH₂Cl₂ / 0.5 h

8.1: O₃ / CH₂Cl₂ / 0.03 h / -78 °C

8.2: 18 percent / NaBH₄/Al₂O₃ / benzene / 14 h / 20 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; N-methyl-2-indolinone; tetrapropylammonium perruthennate; zirconocene dichloride; L-(+)-diisopropyl tartrate; 4 A molecular sieve; potassium hexamethylsilazane; potassium carbonate; ozone; 3-chloro-benzenecarboperoxoic acid; dichloro bis(acetonitrile) palladium(II); In tetrahydrofuran; 2,2,4-trimethylpentane; hexane; dichloromethane; 1,2-dichloro-ethane; N,N-dimethyl-formamide; toluene; acetonitrile; 1.1: Addition / 1.2: Iodination / 2.1: Stille coupling / 3.1: Epoxidation / 4.1: Oxidation / 5.1: Wittig methylenation / 6.1: Carbonylation / 6.2: Oxidation / 7.1: Epoxidation / 8.1: Oxidation / 8.2: Reduction;