4,14-bis[(4-methylphenyl)sulfonyl]-3,4,5,6,9,10,13,14,15,16-decahydro-2H,8H,12H-1,17,7,11,4,14-benzotetrathiadiazacyclononadecin-19,20-dicarbonitrile

Base Information

• Chemical Name: 4,14-bis[(4-methylphenyl)sulfonyl]-3,4,5,6,9,10,13,14,15,16-decahydro-2H,8H,12H-1,17,7,11,4,14-benzotetrathiadiazacyclononadecin-19,20-dicarbonitrile
• CAS No.: 1290601-89-6
• Molecular Formula: C₃₃H₃₈N₄O₄S₆
• Molecular Weight: 747.085
• Mol file: 1290601-89-6.mol

Synonyms:4,14-bis[(4-methylphenyl)sulfonyl]-3,4,5,6,9,10,13,14,15,16-decahydro-2H,8H,12H-1,17,7,11,4,14-benzotetrathiadiazacyclononadecin-19,20-dicarbonitrile

Chemical Property of 4,14-bis[(4-methylphenyl)sulfonyl]-3,4,5,6,9,10,13,14,15,16-decahydro-2H,8H,12H-1,17,7,11,4,14-benzotetrathiadiazacyclononadecin-19,20-dicarbonitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,14-bis[(4-methylphenyl)sulfonyl]-3,4,5,6,9,10,13,14,15,16-decahydro-2H,8H,12H-1,17,7,11,4,14-benzotetrathiadiazacyclononadecin-19,20-dicarbonitrile

There total 1 articles about 4,14-bis[(4-methylphenyl)sulfonyl]-3,4,5,6,9,10,13,14,15,16-decahydro-2H,8H,12H-1,17,7,11,4,14-benzotetrathiadiazacyclononadecin-19,20-dicarbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

N,N′-((propane-1,3-diylbis(sulfanediyl))bis(ethane-2,1-diyl))bis(4-methylbenzenesulfonamide) (1023911-63-8) + 1,2-bis(2-iodomercaptoethyl)-4,5-dicyanobenzene → 4,14-bis[(4-methylphenyl)sulfonyl]-3,4,5,6,9,10,13,14,15,16-decahydro-2H,8H,12H-1,17,7,11,4,14-benzotetrathiadiazacyclononadecin-19,20-dicarbonitrile (1290601-89-6)

Guidance literature:

N,N′-((propane-1,3-diylbis(sulfanediyl))bis(ethane-2,1-diyl))bis(4-methylbenzenesulfonamide); With potassium carbonate; In N,N-dimethyl-formamide; at 50 ℃; for 2h; Inert atmosphere;

1,2-bis(2-iodomercaptoethyl)-4,5-dicyanobenzene; In N,N-dimethyl-formamide; at 50 ℃; for 147h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2011.01.035

Reference yield: 59.0%

4,14-bis[(4-methylphenyl)sulfonyl]-3,4,5,6,9,10,13,14,15,16-decahydro-2H,8H,12H-1,17,7,11,4,14-benzotetrathiadiazacyclononadecin-19,20-dicarbonitrile (1290601-89-6) → C132H152N16O16PbS24

Guidance literature:

With 2-(N,N-dimethylamino)ethanol; lead(II) oxide; at 175 ℃; for 0.1h; Inert atmosphere; Microwave irradiation;

DOI:10.1016/j.jorganchem.2011.01.035

Reference yield: 59.0%

2-(N,N-dimethylamino)ethanol (108-01-0) + 4,14-bis[(4-methylphenyl)sulfonyl]-3,4,5,6,9,10,13,14,15,16-decahydro-2H,8H,12H-1,17,7,11,4,14-benzotetrathiadiazacyclononadecin-19,20-dicarbonitrile (1290601-89-6) + lead(II) oxide → lead(II) tetrathiadi(aza(4-methylphenyl)sulfonyl)phthalocyanine

Guidance literature:

In ethanol; other Radiation; Schlenk techniques under N2 used, mixt. of (NC)2C17H24S4N2(Ts)2 (0.13 mmol), PbO (0.033 mmol) and (2-methylamino)ethanol (2 ml) irradiated at 175°C, 350W for 9 min, cooled to room temp., refluxed with EtOH; filtered, washed with hot ethanol and methanol, dried in vac. over P2O5,chromd. (silica gel, CHCl3:MeOH (9:1)); elem. anal.;

DOI:10.1016/j.jorganchem.2011.01.035

upstream raw materials:

N,N′-((propane-1,3-diylbis(sulfanediyl))bis(ethane-2,1-diyl))bis(4-methylbenzenesulfonamide)