trans-Fe(CO)3(P(Cy)3)2

Base Information

• Chemical Name: trans-Fe(CO)3(P(Cy)3)2
• CAS No.: 40697-14-1
• Molecular Formula: C₃₉H₆₆FeO₃P₂
• Molecular Weight: 700.746
• Mol file: 40697-14-1.mol

Synonyms:trans-Fe(CO)3(P(Cy)3)2

Chemical Property of trans-Fe(CO)3(P(Cy)3)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-Fe(CO)3(P(Cy)3)2

There total 9 articles about trans-Fe(CO)3(P(Cy)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + tricyclohexylphosphine (2622-14-2) → [Fe(CO)3(PCy3)2] (25921-51-1,40697-14-1)

Guidance literature:

In benzene; for 16h; Irradiation; Inert atmosphere;

DOI:10.1021/acs.organomet.6b00045

Reference yield: 62.0%

FeI2(CO)3PCy3 + 1,2-diamino-benzene (95-54-5) → trans-Fe(CO)3(P(Cy)3)2 (40697-14-1) + C26H37FeN2O2P

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; for 2.5h; Schlenk technique; Inert atmosphere;

DOI:10.1016/S1872-2067(15)60920-2

Reference yield: 61.0%

sodium tetrahydroborate (16940-66-2) + iron pentacarbonyl (13463-40-6,37220-42-1) + tricyclohexylphosphine (2622-14-2) → trans-Fe(CO)3(P(Cy)3)2 (40697-14-1)

Guidance literature:

In butan-1-ol; byproducts: H2; (N2); addn. of Fe(CO)5 to a stirred mixt. of P(Cy)3 and NaBH4 and reflux the mixt. after gas evolution for 2 h; then cooling the mixt. to room temp. and placing it in a freezer at 5°C for 12 h;; filtration and washing (CH3OH) of the resulting ppt.; treatment with CH2Cl2 and filtration again; collecting of the product by filtration after addn. of CH3OH and standing of the mixt. in a freezer for several hours;;

DOI:10.1021/om00102a006

upstream raw materials:

triiron dodecarbonyl

tricyclohexylphosphine

sodium tetrahydroborate

iron pentacarbonyl

Downstream raw materials:

Fe(CO)3(P(C₆H₁₁)3)2⁽¹⁺⁾*PF₆^(1-) = {Fe(CO)3(P(C₆H₁₁)3)2}PF₆