(1'R,4S,6S)-4-benzyloxy-2,3-dihydro-2-hydroxymethyl-6-(2-hydroxy-1-phenylethoxy)-4H-pyran

Base Information

Chemical Name:(1'R,4S,6S)-4-benzyloxy-2,3-dihydro-2-hydroxymethyl-6-(2-hydroxy-1-phenylethoxy)-4H-pyran
CAS No.:256397-88-3
Molecular Formula:C₂₁H₂₄O₅
Molecular Weight:356.419
Hs Code.:

Synonyms:(1'R,4S,6S)-4-benzyloxy-2,3-dihydro-2-hydroxymethyl-6-(2-hydroxy-1-phenylethoxy)-4H-pyran

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Chemical Property of (1'R,4S,6S)-4-benzyloxy-2,3-dihydro-2-hydroxymethyl-6-(2-hydroxy-1-phenylethoxy)-4H-pyran

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Technology Process of (1'R,4S,6S)-4-benzyloxy-2,3-dihydro-2-hydroxymethyl-6-(2-hydroxy-1-phenylethoxy)-4H-pyran

There total 5 articles about (1'R,4S,6S)-4-benzyloxy-2,3-dihydro-2-hydroxymethyl-6-(2-hydroxy-1-phenylethoxy)-4H-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 207557-97-9
(4S,6S)-4-Benzyloxy-6-((R)-butoxycarbonyl-phenyl-methoxy)-5,6-dihydro-4H-pyran-2-carboxylic acid methyl ester

: 256397-88-3
(1'R,4S,6S)-4-benzyloxy-2,3-dihydro-2-hydroxymethyl-6-(2-hydroxy-1-phenylethoxy)-4H-pyran

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran;
DOI:10.1016/0040-4039(96)00769-1

Reference yield:

: 179924-43-7
methyl trans-4-benzyloxy-2-oxo-3-butenoate

: 256397-88-3
(1'R,4S,6S)-4-benzyloxy-2,3-dihydro-2-hydroxymethyl-6-(2-hydroxy-1-phenylethoxy)-4H-pyran

Guidance literature:: Multi-step reaction with 2 steps

1: Eu(fod)3 / petroleum ether; toluene / Heating

2: 85 percent / LiAlH₄ / diethyl ether / 15 h / 20 °C

With lithium aluminium tetrahydride; Eu(fod)3; In diethyl ether; toluene; Petroleum ether; 1: Cyclization / 2: Reduction;
DOI:10.1002/(SICI)1099-0690(199911)1999:11<2885::AID-EJOC2885>3.0.CO;2-J

Reference yield:

: 164386-44-1
(R)-Phenyl-vinyloxy-acetic acid butyl ester

: 256397-88-3
(1'R,4S,6S)-4-benzyloxy-2,3-dihydro-2-hydroxymethyl-6-(2-hydroxy-1-phenylethoxy)-4H-pyran

Guidance literature:: Multi-step reaction with 2 steps

1: Eu(fod)3 / petroleum ether; toluene / Heating

2: 85 percent / LiAlH₄ / diethyl ether / 15 h / 20 °C

With lithium aluminium tetrahydride; Eu(fod)3; In diethyl ether; toluene; Petroleum ether; 1: Cyclization / 2: Reduction;
DOI:10.1002/(SICI)1099-0690(199911)1999:11<2885::AID-EJOC2885>3.0.CO;2-J