[Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pt(PPh₃)Cl][PF₆]

Base Information

• Chemical Name: [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pt(PPh₃)Cl][PF₆]
• CAS No.: 847830-71-1
• Molecular Formula: C₂₉H₃₉ClN₂NiPPtS₂*F₆P
• Molecular Weight: 944.935
• Mol file: 847830-71-1.mol

Synonyms:[Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pt(PPh₃)Cl][PF₆]

Chemical Property of [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pt(PPh₃)Cl][PF₆]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pt(PPh₃)Cl][PF₆]

There total 1 articles about [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pt(PPh₃)Cl][PF₆] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

sodium hexaflorophosphate + trans-dichlorobis(triphenylphosphine)platinum(II) (14056-88-3) + [N,N'-diethyl-3,7-diazanonane-1,9-dithiolato]nickel(II) (176445-58-2) → [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pt(PPh3)Cl][PF6] (847830-71-1)

Guidance literature:

In acetonitrile; under pure N2 atm.; to soln. of Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate) in MeCN added suspn. of trans-Pt(PPh3)2Cl2 in MeCN; mixt. stirred for 10 min; soln. treated with NaPF6 in MeCN; stirred for 2.5 h; mixt. filtered through Celite; filtrate evapd. to dryness; solid dissolved in MeCN; filtered; ether was diffused into filtrate;

DOI:10.1021/ja040222n

Reference yield:

(Bu4N)2[Fe4S4(1,3,5-tris-((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris-(p-tolylthio)benzenate(3-))(SC2H5)] (137003-15-7) + [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pt(PPh3)Cl][PF6] (847830-71-1) → [Fe4S4(1,3,5-tris-((4,6-dimethyl-3-mercaptophenyl)thio)-2,4,6-tris-(p-tolylthio)benzenate(3-))Cl](2-) + [Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolate)Pt(PPh3)(SEt)](1+)

Guidance literature:

In dimethylsulfoxide-d6; monitored by NMR-spectroscopy;

DOI:10.1021/ja040222n

upstream raw materials:

trans-dichlorobis(triphenylphosphine)platinum(II)

[N,N'-diethyl-3,7-diazanonane-1,9-dithiolato]nickel(II)