cis-Dichlorobis(triphenylphosphine)platinum(II)

Base Information

• Chemical Name: cis-Dichlorobis(triphenylphosphine)platinum(II)
• CAS No.: 14056-88-3
• Molecular Formula: C36H30 Cl2 P2 Pt
• Molecular Weight: 790.568
• European Community (EC) Number: 623-707-1,624-549-6
• Mol file: 14056-88-3.mol

Synonyms:cis-Dichlorobis(triphenylphosphine)platinum(II);15604-36-1;14056-88-3;trans-Dichlorobis(triphenylphosphine)platinum(II);cis-Bis(triphenylphosphine)platinum(II) chloride;dichloroplatinum;triphenylphosphane;MFCD00010825;Pt(PPh3)2Cl2;P(c1ccccc1)(c2ccccc2)(c3ccccc3)[Pt](Cl)(Cl)P(c4ccccc4)(c5ccccc5)c6ccccc6;PtCl2(PPh3)2;cis-Dichlorobis(triphenylphosphine)platinum (II);SCHEMBL691327;AKOS015848554;AC-5532;AT34929;SC10692;dichloroplatinum-triphenylphosphane (1:2);FT-0658376;J-520088;cis-Dichlorobis(triphenylphosphine)platinum(II), Premion?;dichlorobis (triphenylphosphine) platinum pound cento pound(c)

Chemical Property of cis-Dichlorobis(triphenylphosphine)platinum(II)

Chemical Property:

• Melting Point: ≥300 °C(lit.)
• PSA: 27.18000
• LogP: 8.26610
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 789.084775
• Heavy Atom Count: 41
• Complexity: 204

Purity/Quality:

97% ^*data from raw suppliers

trans-Dichlorobis(triphenylphosphine)platinum(II) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Pt]Cl
• Uses: Catalyst for:Preparation of soluble polymers of monosubstituted acetylenes with quaternary ammonium pendant groupsAlkynylation and hydrogenation reactionsHetero-Diels-Alder/ring-opening reactionsInsertion of carbenes into O-H bonds of alcoholsCyclopropanation of olefinsHydroformylation reactions

Technology Process of cis-Dichlorobis(triphenylphosphine)platinum(II)

There total 215 articles about cis-Dichlorobis(triphenylphosphine)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

potassium tetrachloroplatinate(II) (10025-99-7) + triphenylphosphine (603-35-0) → cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1)

Guidance literature:

Ar atmosphere; procedure described by Brune et al., Chem. Ber. 117 (1984) 2791-2802;

Reference yield: 98.0%

dihydrogen hexachloroplatinate(IV) hexahydrate → cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1)

Guidance literature:

With triphenylphosphine; In ethanol; molar ratio Pt:P=1:4.5; stirring (room temp., few min), refluxing (1 h); pptn. on cooling, filtration, washing (EtOH, ether), drying (vac.);

DOI:10.1016/S0020-1693(00)88569-2

Reference yield: 98.0%

triphenylphosphine (603-35-0) + platinum(II) chloride (10025-65-7) → cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1)

Guidance literature:

In neat (no solvent); ball-milling of crystalline PtCl2 with PPh3 (2 molar equiv.) at room temp. for 1 or 2 h; powder dissolved in CH2Cl2, soln. filtered, solvent evapd.;

DOI:10.1039/b203694k

upstream raw materials:

triphenylphosphine

ethylenebis(triphenylphosphine)platinum⁽⁰⁾

potassium trichloro(ethene)platinate(II)

tetrachloromethane

Downstream raw materials:

dichloro bis(acetonitrile) palladium(II)

Pt(P(C₆H₅)3)2(NO₂)Cl

tetrakis(triphenylphosphine)platinum

((C₆H₅)3P)2PtClF