Technology Process of C45H87NO15Si8
There total 5 articles about C45H87NO15Si8 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
dibutyltin dilaurate;
In
dichloromethane;
at 20 ℃;
for 18h;
Inert atmosphere;
DOI:10.1002/cssc.201200466
- Guidance literature:
-
Multi-step reaction with 4 steps
1: acetic acid; bromine / dichloromethane / 3 h / 0 - 20 °C
2: tetrakis(triphenylphosphine) palladium(0) / toluene / 18 h / 110 °C / Schlenk technique; Inert atmosphere
3: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 - 20 °C
4: dibutyltin dilaurate / dichloromethane / 18 h / 20 °C / Inert atmosphere
With
lithium aluminium tetrahydride; tetrakis(triphenylphosphine) palladium(0); bromine; dibutyltin dilaurate; acetic acid;
In
tetrahydrofuran; dichloromethane; toluene;
2: |Stille Cross Coupling;
DOI:10.1002/cssc.201200466
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: caesium carbonate; potassium carbonate / N,N-dimethyl-formamide / 1 h / 20 °C
1.2: 16 h
2.1: acetic acid; bromine / dichloromethane / 3 h / 0 - 20 °C
3.1: tetrakis(triphenylphosphine) palladium(0) / toluene / 18 h / 110 °C / Schlenk technique; Inert atmosphere
4.1: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 - 20 °C
5.1: dibutyltin dilaurate / dichloromethane / 18 h / 20 °C / Inert atmosphere
With
lithium aluminium tetrahydride; tetrakis(triphenylphosphine) palladium(0); bromine; dibutyltin dilaurate; potassium carbonate; caesium carbonate; acetic acid;
In
tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene;
3.1: |Stille Cross Coupling;
DOI:10.1002/cssc.201200466
