phenyl 4-O-benzoyl-2,3-O-carbonyl-1-thio-α-L-rhamnopyranoside

Base Information

• Chemical Name: phenyl 4-O-benzoyl-2,3-O-carbonyl-1-thio-α-L-rhamnopyranoside
• CAS No.: 526199-47-3
• Molecular Formula: C₂₀H₁₈O₆S
• Molecular Weight: 386.425
• Mol file: 526199-47-3.mol

Synonyms:phenyl 4-O-benzoyl-2,3-O-carbonyl-1-thio-α-L-rhamnopyranoside

Chemical Property of phenyl 4-O-benzoyl-2,3-O-carbonyl-1-thio-α-L-rhamnopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl 4-O-benzoyl-2,3-O-carbonyl-1-thio-α-L-rhamnopyranoside

There total 1 articles about phenyl 4-O-benzoyl-2,3-O-carbonyl-1-thio-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phosgene (75-44-5) + phenyl 4-O-benzoyl-1-thio-α-L-rhamnopyranoside (145836-09-5) → phenyl 4-O-benzoyl-2,3-O-carbonyl-1-thio-α-L-rhamnopyranoside (526199-47-3)

Guidance literature:

With pyridine; In toluene; for 2h;

DOI:10.1021/jo035003j

Reference yield: 85.0%

methyl 2,3,4-tri-O-acetyl-α-D-glucopyranose (7432-72-6) + phenyl 4-O-benzoyl-2,3-O-carbonyl-1-thio-α-L-rhamnopyranoside (526199-47-3) → methyl 2,3,4-tri-O-acetyl-6-O-(4-O-benzoyl-2,3-O-carbonyl-α,β-L-rhamnopyranosyl)-α-D-glucopyranoside

Guidance literature:

phenyl 4-O-benzoyl-2,3-O-carbonyl-1-thio-α-L-rhamnopyranoside; With 1,1'-sulfinylbisbenzene; 2,4,5-tri-tert-butylpyrimidine; trifluoromethanesulfonic acid anhydride; In dichloromethane; at -60 ℃; for 0.0833333h;

methyl 2,3,4-tri-O-acetyl-α-D-glucopyranose; In dichloromethane; at -60 - 20 ℃;

DOI:10.1021/ol034312t

Reference yield: 72.0%

Cholestanol (80-97-7) + phenyl 4-O-benzoyl-2,3-O-carbonyl-1-thio-α-L-rhamnopyranoside (526199-47-3) → 3β-cholestanyl 4-O-benzoyl-2,3-O-carbonyl-α-L-rhamnopyranoside

Guidance literature:

phenyl 4-O-benzoyl-2,3-O-carbonyl-1-thio-α-L-rhamnopyranoside; With 1-benzenesulfinyl piperidine; trifluoromethylsulfonic anhydride; 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; at -60 ℃; for 0.333333h;

Cholestanol; In dichloromethane; at -60 ℃; for 1h;

DOI:10.1021/jo035003j

upstream raw materials:

phosgene

phenyl 4-O-benzoyl-1-thio-α-L-rhamnopyranoside

Downstream raw materials:

4-O-benzoyl-2,3-O-carbonyl-α-L-rhamnopyranosyl bromide