[Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2]⁽²⁺⁾*2ClO₄^(1-)*2CH₃CN=[Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2](ClO₄)2*2CH₃CN

Base Information

• Chemical Name: [Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2]⁽²⁺⁾*2ClO₄^(1-)*2CH₃CN=[Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2](ClO₄)2*2CH₃CN
• CAS No.: 96633-02-2
• Molecular Formula: 2C₂H₃N*C₅₈H₅₀N₄Ni₂P₄*2ClO₄
• Molecular Weight: 1325.34

Synonyms:[Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2]⁽²⁺⁾*2ClO₄^(1-)*2CH₃CN=[Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2](ClO₄)2*2CH₃CN

Chemical Property of [Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2]⁽²⁺⁾*2ClO₄^(1-)*2CH₃CN=[Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2](ClO₄)2*2CH₃CN

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Technology Process of [Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2]⁽²⁺⁾*2ClO₄^(1-)*2CH₃CN=[Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2](ClO₄)2*2CH₃CN

There total 1 articles about [Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2]⁽²⁺⁾*2ClO₄^(1-)*2CH₃CN=[Ni₂[C₃HN₂(CH₂P(C₆H₅)2)2]2](ClO₄)2*2CH₃CN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

nickel(II) perchlorate hexahydrate + 3,5-bis(chloromethyl)pyrazole hydrochloride (96616-82-9) + acetonitrile (75-05-8,26809-02-9) → [Ni2[C3HN2(CH2P(C6H5)2)2]2](2+)*2ClO4(1-)*2CH3CN=[Ni2[C3HN2(CH2P(C6H5)2)2]2](ClO4)2*2CH3CN (96633-02-2)

Guidance literature:

With lithium; acetic acid; triphenylphosphine; In tetrahydrofuran; ethanol; under N2, addn. of the pyrazole to a cooled soln. of Li metal and PPh3 in THF, then addn. of ethanol, acetic acid and a soln. of Ni(ClO4)2 in EtOH, filtn. of soln., dissolution in boiling CH3CN; filtn., addn. of ether, elem. anal. of ppt.;

Reference yield: 92.0%

tetracarbonyldi-μ-chlorodirhodium(I) + [Ni2[C3HN2(CH2P(C6H5)2)2]2](2+)*2ClO4(1-)*2CH3CN=[Ni2[C3HN2(CH2P(C6H5)2)2]2](ClO4)2*2CH3CN (96633-02-2) → [Rh2(Cl)(CO)2(C3HN2(CH2P(C6H5)2)2)] (96532-16-0)

Guidance literature:

In methanol; acetonitrile; under N2 or Ar, addn. of MeOH to soln. of Rh- and Ni-complex, reflux for 1 h; mixt. is cooled to 0°C, filtn. in airppt. is washed with MeOH, EtOH, and ether and dried, recrystn. from benzene/hexane, elem. anal.;

Reference yield: 86.0%

[Ni2[C3HN2(CH2P(C6H5)2)2]2](2+)*2ClO4(1-)*2CH3CN=[Ni2[C3HN2(CH2P(C6H5)2)2]2](ClO4)2*2CH3CN (96633-02-2) + palladium dichloride → [Pd2(Cl)Cl2(C3HN2(CH2P(C6H5)2)2)] (96616-74-9)

Guidance literature:

With lithium chloride; In dimethyl sulfoxide; under N2 or Ar, addn. of solid LiCl to soln. of PdCl2, then addn. of solid Ni-complex, mixt. is stirred and heated for 15 min at 150°C; addn. of H2O, recrystn. of ppt. from hot Me2SO/H2O, elem. anal.;

upstream raw materials:

3,5-bis(chloromethyl)pyrazole hydrochloride

acetonitrile

Downstream raw materials:

[Rh₂(Cl)(CO)2(C₃HN₂(CH₂P(C₆H₅)2)2)]

[Rh₂(C₇H₈)2(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)=[Rh₂(C₇H₈)2(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄

[Pd₂(Cl)Cl₂(C₃HN₂(CH₂P(C₆H₅)2)2)]

[Ir₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*CH₃OH=[Ir₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*CH₃OH

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