Technology Process of C25H38N2O6Si
There total 6 articles about C25H38N2O6Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C25H36N2O5Si;
With
9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 20.5h;
With
dihydrogen peroxide; sodium hydroxide;
In
tetrahydrofuran; methanol; water;
at 0 - 20 ℃;
for 5h;
DOI:10.1016/j.bmcl.2014.04.042
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: Dess-Martin periodane / acetonitrile / 2 h / Reflux
2.1: 0 - 20 °C
3.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / acetonitrile / 0.08 h / 0 °C
3.2: 20 °C
4.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 20.5 h / 0 - 20 °C
4.2: 5 h / 0 - 20 °C
With
Dess-Martin periodane; 1,8-diazabicyclo[5.4.0]undec-7-ene; 9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran; acetonitrile;
2.1: |Wittig Olefination;
DOI:10.1016/j.bmcl.2014.04.042
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: pyridine / 23 h / 20 - 70 °C
2.1: trifluoroacetic acid; water / dichloromethane / 1.25 h / 20 °C / Cooling with ice
3.1: Dess-Martin periodane / acetonitrile / 2 h / Reflux
4.1: 0 - 20 °C
5.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / acetonitrile / 0.08 h / 0 °C
5.2: 20 °C
6.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 20.5 h / 0 - 20 °C
6.2: 5 h / 0 - 20 °C
With
pyridine; water; Dess-Martin periodane; 1,8-diazabicyclo[5.4.0]undec-7-ene; 9-bora-bicyclo[3.3.1]nonane; trifluoroacetic acid;
In
tetrahydrofuran; dichloromethane; acetonitrile;
4.1: |Wittig Olefination;
DOI:10.1016/j.bmcl.2014.04.042
