2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-2-phenyl-7-(2,2,2-trichloro-ethoxycarbonylamino)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Base Information

Chemical Name:2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-2-phenyl-7-(2,2,2-trichloro-ethoxycarbonylamino)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester
CAS No.:391860-83-6
Molecular Formula:C₂₅H₂₄Cl₆N₂O₇
Molecular Weight:677.193
Hs Code.:

2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-2-phenyl-7-(2,2,2-trichloro-ethoxycarbonylamino)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Synonyms:2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-2-phenyl-7-(2,2,2-trichloro-ethoxycarbonylamino)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-2-phenyl-7-(2,2,2-trichloro-ethoxycarbonylamino)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-2-phenyl-7-(2,2,2-trichloro-ethoxycarbonylamino)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

There total 4 articles about 2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-2-phenyl-7-(2,2,2-trichloro-ethoxycarbonylamino)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 545-06-2
trichloroacetonitrile

: ((2R,4aR,7R,8R,8aS)-8-Benzyloxy-6-hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-carbamic acid 2,2,2-trichloro-ethyl ester

: 391860-83-6
2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-2-phenyl-7-(2,2,2-trichloro-ethoxycarbonylamino)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Guidance literature:: With caesium carbonate; In dichloromethane;
DOI:10.1016/S0040-4039(01)01619-7

Reference yield:

: 100-39-0
benzyl bromide

: 391860-83-6
2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-2-phenyl-7-(2,2,2-trichloro-ethoxycarbonylamino)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 87 percent / AgO / CH₂Cl₂

2.1: H₂ / Ir complex / tetrahydrofuran

2.2: 99 percent / I₂ / H₂O

3.1: 100 percent / Cs₂CO₃ / CH₂Cl₂

With silver(II) oxide; hydrogen; caesium carbonate; iridium; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(01)01619-7

Reference yield:

: 183388-21-8
allyl 4,6-O-benzylidene-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranoside

: 391860-83-6
2,2,2-Trichloro-acetimidic acid (2R,4aR,7R,8R,8aS)-8-benzyloxy-2-phenyl-7-(2,2,2-trichloro-ethoxycarbonylamino)-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 87 percent / AgO / CH₂Cl₂

2.1: H₂ / Ir complex / tetrahydrofuran

2.2: 99 percent / I₂ / H₂O

3.1: 100 percent / Cs₂CO₃ / CH₂Cl₂

With silver(II) oxide; hydrogen; caesium carbonate; iridium; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0040-4039(01)01619-7