(-)-(1E,3S)-5-((acetyloxy)methyl)-1-((1S)-1-((benzylamino)sulfonyl)ethyl)-2-methyl-3-((1S)-1-phenylethoxy)hexa-1,5-dien-1-yl benzoate

Base Information

Chemical Name:(-)-(1E,3S)-5-((acetyloxy)methyl)-1-((1S)-1-((benzylamino)sulfonyl)ethyl)-2-methyl-3-((1S)-1-phenylethoxy)hexa-1,5-dien-1-yl benzoate
CAS No.:872321-41-0
Molecular Formula:C₃₄H₃₉NO₇S
Molecular Weight:605.752
Hs Code.:

Synonyms:(-)-(1E,3S)-5-((acetyloxy)methyl)-1-((1S)-1-((benzylamino)sulfonyl)ethyl)-2-methyl-3-((1S)-1-phenylethoxy)hexa-1,5-dien-1-yl benzoate

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Chemical Property of (-)-(1E,3S)-5-((acetyloxy)methyl)-1-((1S)-1-((benzylamino)sulfonyl)ethyl)-2-methyl-3-((1S)-1-phenylethoxy)hexa-1,5-dien-1-yl benzoate

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Technology Process of (-)-(1E,3S)-5-((acetyloxy)methyl)-1-((1S)-1-((benzylamino)sulfonyl)ethyl)-2-methyl-3-((1S)-1-phenylethoxy)hexa-1,5-dien-1-yl benzoate

There total 4 articles about (-)-(1E,3S)-5-((acetyloxy)methyl)-1-((1S)-1-((benzylamino)sulfonyl)ethyl)-2-methyl-3-((1S)-1-phenylethoxy)hexa-1,5-dien-1-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Benzoic acid (E)-(S)-5-acetoxymethyl-1-((R)-1-chlorosulfonyl-ethyl)-2-methyl-3-((S)-1-phenyl-ethoxy)-hexa-1,5-dienyl ester

: 100-46-9
benzylamine

: 872321-43-2
(-)-(1E,3S)-5-((acetyloxy)methyl)-1-((1R)-1-((benzylamino)sulfonyl)ethyl)-2-methyl-3-((1S)-1-phenylethoxy)hexa-1,5-dien-1-yl benzoate

: 872321-41-0
(-)-(1E,3S)-5-((acetyloxy)methyl)-1-((1S)-1-((benzylamino)sulfonyl)ethyl)-2-methyl-3-((1S)-1-phenylethoxy)hexa-1,5-dien-1-yl benzoate

Guidance literature:: With pyridine; In acetonitrile; at -20 - 20 ℃; for 6.5h;
DOI:10.1016/j.tet.2005.08.067

Reference yield:

: C₃₀H₄₀O₇SSi

: 872321-41-0
(-)-(1E,3S)-5-((acetyloxy)methyl)-1-((1S)-1-((benzylamino)sulfonyl)ethyl)-2-methyl-3-((1S)-1-phenylethoxy)hexa-1,5-dien-1-yl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: N-chlorosuccinimide / acetonitrile / 0.5 h / -40 - -30 °C

2: 2.85 g / pyridine / acetonitrile / 6.5 h / -20 - 20 °C

With pyridine; N-chloro-succinimide; In acetonitrile;
DOI:10.1016/j.tet.2005.08.067

Reference yield:

: 72047-94-0
[2-(acetoxymethyl)prop-2-enyl]trimethylsilane

: 872321-41-0
(-)-(1E,3S)-5-((acetyloxy)methyl)-1-((1S)-1-((benzylamino)sulfonyl)ethyl)-2-methyl-3-((1S)-1-phenylethoxy)hexa-1,5-dien-1-yl benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: SO₂; Tf₂NSiMe₃ / CH₂Cl₂ / 16 h / -78 °C

2: N-chlorosuccinimide / acetonitrile / 0.5 h / -40 - -30 °C

3: 2.85 g / pyridine / acetonitrile / 6.5 h / -20 - 20 °C

With pyridine; N-chloro-succinimide; sulfur dioxide; trimethylsilyl bis(trifluoromethanesulfonyl)imide; In dichloromethane; acetonitrile;
DOI:10.1016/j.tet.2005.08.067