erythro-5,6-bis<4-(tert-butyldimethylsiloxy)phenyl>-1-octyl chloroacetate

Base Information

Chemical Name:erythro-5,6-bis<4-(tert-butyldimethylsiloxy)phenyl>-1-octyl chloroacetate
CAS No.:120578-87-2
Molecular Formula:C₃₄H₅₅ClO₄Si₂
Molecular Weight:619.432
Hs Code.:

Synonyms:erythro-5,6-bis<4-(tert-butyldimethylsiloxy)phenyl>-1-octyl chloroacetate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of erythro-5,6-bis<4-(tert-butyldimethylsiloxy)phenyl>-1-octyl chloroacetate

Chemical Property:

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Technology Process of erythro-5,6-bis<4-(tert-butyldimethylsiloxy)phenyl>-1-octyl chloroacetate

There total 7 articles about erythro-5,6-bis<4-(tert-butyldimethylsiloxy)phenyl>-1-octyl chloroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: tert-butyl 6-hydroxy-5,6-bis(4-methoxyphenyl)octanoate

: 120578-87-2
erythro-5,6-bis<4-(tert-butyldimethylsiloxy)phenyl>-1-octyl chloroacetate

Guidance literature:: Multi-step reaction with 6 steps

1: 45.5 percent / H₂, perchloric acid / Pd/C / acetic acid / 2250.2 Torr

2: 93 percent / BBr₃ / CH₂Cl₂ / 3.5 h / Ambient temperature

3: imidazole / dimethylformamide / 12 h / Ambient temperature

4: methanol / dimethylformamide / 1 h / Ambient temperature

5: 86 percent / lithium aluminum hydride / tetrahydrofuran / 4 h

6: 75 mg / pyridine / diethyl ether / 1 h

With pyridine; 1H-imidazole; methanol; lithium aluminium tetrahydride; perchloric acid; hydrogen; boron tribromide; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; dichloromethane; acetic acid; N,N-dimethyl-formamide;
DOI:10.1021/jm00127a023

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 120578-87-2
erythro-5,6-bis<4-(tert-butyldimethylsiloxy)phenyl>-1-octyl chloroacetate

Guidance literature:: Multi-step reaction with 4 steps

1: imidazole / dimethylformamide / 12 h / Ambient temperature

2: methanol / dimethylformamide / 1 h / Ambient temperature

3: 86 percent / lithium aluminum hydride / tetrahydrofuran / 4 h

4: 75 mg / pyridine / diethyl ether / 1 h

With pyridine; 1H-imidazole; methanol; lithium aluminium tetrahydride; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jm00127a023

Reference yield:

: 107036-39-5,120578-90-7
(5S*,6R*)-5,6-bis(4-hydroxyphenyl)octanoic acid

: 120578-87-2
erythro-5,6-bis<4-(tert-butyldimethylsiloxy)phenyl>-1-octyl chloroacetate

Guidance literature:: Multi-step reaction with 4 steps

1: imidazole / dimethylformamide / 12 h / Ambient temperature

2: methanol / dimethylformamide / 1 h / Ambient temperature

3: 86 percent / lithium aluminum hydride / tetrahydrofuran / 4 h

4: 75 mg / pyridine / diethyl ether / 1 h

With pyridine; 1H-imidazole; methanol; lithium aluminium tetrahydride; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jm00127a023