trans-bis(1,2-diphenylphosphanylethane)(chloro)(C₃(CH₃)2)ruthenium BF₄

Base Information

• Chemical Name: trans-bis(1,2-diphenylphosphanylethane)(chloro)(C₃(CH₃)2)ruthenium BF₄
• CAS No.: 505094-05-3
• Molecular Formula: BF₄*C₅₇H₅₄ClP₄Ru
• Molecular Weight: 1086.28
• Mol file: 505094-05-3.mol

Synonyms:trans-bis(1,2-diphenylphosphanylethane)(chloro)(C₃(CH₃)2)ruthenium BF₄

Chemical Property of trans-bis(1,2-diphenylphosphanylethane)(chloro)(C₃(CH₃)2)ruthenium BF₄

Chemical Property:

Purity/Quality:

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Technology Process of trans-bis(1,2-diphenylphosphanylethane)(chloro)(C₃(CH₃)2)ruthenium BF₄

There total 3 articles about trans-bis(1,2-diphenylphosphanylethane)(chloro)(C₃(CH₃)2)ruthenium BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

[(1,2-bis(diphenylphosphino)ethane)2RuCl]BF4 (151840-73-2) + 2-methyl-but-3-yn-2-ol (115-19-5) → trans-bis(1,2-diphenylphosphanylethane)(chloro)(C3(CH3)2)ruthenium BF4 (505094-05-3)

Guidance literature:

In dichloromethane; (inert atmosphere); dissolving in CH2Cl2 ruthenium compd. and alcohol deriv., stirring for 18 h at room temp.; Selegue J.P. Organometallics 1982, 1, 217-218; filtration, evapn., washing with ether, recrystn. (CH2Cl2/pentane), elem. anal.;

DOI:10.1021/ja0603453

Reference yield:

trans-[Cl(1,2-bis(diphenylphosphino)ethane)2Ru(II)CCHCMe2](BF4)2 → trans-bis(1,2-diphenylphosphanylethane)(chloro)(C3(CH3)2)ruthenium BF4 (505094-05-3)

Guidance literature:

With acetone; In dichloromethane-d2; under inert atmosphere; acetone added to CD2Cl2 soln. of Ru complex; not isolated;

DOI:10.1021/om0304098

Reference yield:

tetrafluoroboric acid diethyl ether (67969-82-8) + trans-[Cl(1,2-bis(diphenylphosphino)ethane)2Ru(II)CCC(Me)=CH2] → trans-bis(1,2-diphenylphosphanylethane)(chloro)(C3(CH3)2)ruthenium BF4 (505094-05-3)

Guidance literature:

In not given; under inert atmosphere; 1 equiv. of HBF4*Et2O;

DOI:10.1021/om0304098

upstream raw materials:

[(1,2-bis(diphenylphosphino)ethane)2RuCl]BF₄

2-methyl-but-3-yn-2-ol

tetrafluoroboric acid diethyl ether