(E)-2-(((4-methoxybenzyl)oxy)methyl)-6,10-dimethylundeca-1,5,10-trien-4-ol

Base Information

Chemical Name:(E)-2-(((4-methoxybenzyl)oxy)methyl)-6,10-dimethylundeca-1,5,10-trien-4-ol
CAS No.:1432620-61-5
Molecular Formula:C₂₂H₃₂O₃
Molecular Weight:344.494
Hs Code.:

Synonyms:(E)-2-(((4-methoxybenzyl)oxy)methyl)-6,10-dimethylundeca-1,5,10-trien-4-ol

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Chemical Property of (E)-2-(((4-methoxybenzyl)oxy)methyl)-6,10-dimethylundeca-1,5,10-trien-4-ol

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Technology Process of (E)-2-(((4-methoxybenzyl)oxy)methyl)-6,10-dimethylundeca-1,5,10-trien-4-ol

There total 6 articles about (E)-2-(((4-methoxybenzyl)oxy)methyl)-6,10-dimethylundeca-1,5,10-trien-4-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1432620-60-4
(E)-2-(((4-methoxybenzyl)oxy)methyl)-6,10-dimethylundeca-1,5,10-trien-4-one

: 1432620-61-5
(E)-2-(((4-methoxybenzyl)oxy)methyl)-6,10-dimethylundeca-1,5,10-trien-4-ol

Guidance literature:: With dimethyl sulfide borane; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran; at -78 ℃; for 3h; enantioselective reaction;
DOI:10.1039/c3ob40120k

Reference yield:

: 20038-12-4
4-bromo-2-methylbut-1-ene

: 1432620-61-5
(E)-2-(((4-methoxybenzyl)oxy)methyl)-6,10-dimethylundeca-1,5,10-trien-4-ol

Guidance literature:: Multi-step reaction with 6 steps

1.1: lithium diisopropyl amide / tetrahydrofuran / -78 °C

2.1: lithium hydroxide / water

3.1: copper(l) cyanide / diethyl ether

4.1: isopropylmagnesium chloride / tetrahydrofuran / 0.5 h

5.1: magnesium; ethylene dibromide / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

5.2: 0.5 h / -78 °C / Inert atmosphere

6.1: (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; dimethyl sulfide borane / tetrahydrofuran / 3 h / -78 °C

With isopropylmagnesium chloride; dimethyl sulfide borane; copper(l) cyanide; magnesium; ethylene dibromide; lithium hydroxide; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; water;
DOI:10.1039/c3ob40120k

Reference yield:

: 110995-23-8
ethyl 7-methyl-3-oxo-7-octenate

: 1432620-61-5
(E)-2-(((4-methoxybenzyl)oxy)methyl)-6,10-dimethylundeca-1,5,10-trien-4-ol

Guidance literature:: Multi-step reaction with 5 steps

1.1: lithium hydroxide / water

2.1: copper(l) cyanide / diethyl ether

3.1: isopropylmagnesium chloride / tetrahydrofuran / 0.5 h

4.1: magnesium; ethylene dibromide / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

4.2: 0.5 h / -78 °C / Inert atmosphere

5.1: (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; dimethyl sulfide borane / tetrahydrofuran / 3 h / -78 °C

With isopropylmagnesium chloride; dimethyl sulfide borane; copper(l) cyanide; magnesium; ethylene dibromide; lithium hydroxide; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran; diethyl ether; water;
DOI:10.1039/c3ob40120k