1,3-bis(2,4,6-trimethylphenyl)diazagermol-2-ylidene

Base Information

• Chemical Name: 1,3-bis(2,4,6-trimethylphenyl)diazagermol-2-ylidene
• CAS No.: 889855-90-7
• Molecular Formula: C₂₀H₂₄GeN₂
• Molecular Weight: 365.014
• Mol file: 889855-90-7.mol

Synonyms:1,3-bis(2,4,6-trimethylphenyl)diazagermol-2-ylidene

Chemical Property of 1,3-bis(2,4,6-trimethylphenyl)diazagermol-2-ylidene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 1,3-bis(2,4,6-trimethylphenyl)diazagermol-2-ylidene

There total 3 articles about 1,3-bis(2,4,6-trimethylphenyl)diazagermol-2-ylidene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

germanium(II) chloride dioxane + N,N'-bis(2,4,6-trimethylphenyl)ethanediimine (56222-36-7) → 1,3-bis(2,4,6-trimethylphenyl)diazagermol-2-ylidene (889855-90-7)

Guidance literature:

With lithium; In tetrahydrofuran; under Ar atm. to N,N'-dimesitylethanediimine and Li THF was added and stirred overnight, soln. was filtered through Celite, GeCl2*dioxane in THFwas added and stirred for 2 h; solvent was removed in vacuo, residue was extd. with pentane, filtered through Celite and evapd., residue was recrystd. from pentane at -20°C; elem. anal.;

DOI:10.1021/ic060050q

Reference yield:

(((CH3)2C6H3NC(CH3))2CH)CuGe(((CH3)3C6H2NCH)2) (889855-78-1) + triphenylphosphine (603-35-0) → 1,3-bis(2,4,6-trimethylphenyl)diazagermol-2-ylidene (889855-90-7) + (((CH3)2C6H3NC(CH3))2CH)Cu(P(C6H5)3) (889855-84-9)

Guidance literature:

In benzene-d6;

DOI:10.1021/ic060050q

Reference yield:

(((CH3)2C6H3NC(CH3))2CH)CuGe(((CH3)3C6H2NCH)2) (889855-78-1) + [1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene (141556-42-5) → 1,3-bis(2,4,6-trimethylphenyl)diazagermol-2-ylidene (889855-90-7) + (((CH3)2C6H3NC(CH3))2CH)CuC(((CH3)3C6H2NCH)2)

Guidance literature:

In benzene-d6;

DOI:10.1021/ic060050q

upstream raw materials:

N,N'-bis(2,4,6-trimethylphenyl)ethanediimine

(((CH₃)2C₆H₃NC(CH₃))2CH)CuGe(((CH₃)3C₆H₂NCH)2)

triphenylphosphine

[1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene

Downstream raw materials:

(((CH₃)2C₆H₃NC(CH₃))2CH)CuGe(((CH₃)3C₆H₂NCH)2)