(S)-2--1-azido-5-<(tert-butyldimethylsilyl)oxy>pentane

Base Information

Chemical Name:(S)-2--1-azido-5-<(tert-butyldimethylsilyl)oxy>pentane
CAS No.:132343-48-7
Molecular Formula:C₂₆H₃₈N₄O₃Si
Molecular Weight:482.698
Hs Code.:

(S)-2-<N-benzyl-N-(benzyloxycarbonyl)amino>-1-azido-5-<(tert-butyldimethylsilyl)oxy>pentane

Synonyms:(S)-2--1-azido-5-<(tert-butyldimethylsilyl)oxy>pentane

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Chemical Property of (S)-2--1-azido-5-<(tert-butyldimethylsilyl)oxy>pentane

Chemical Property:

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Technology Process of (S)-2--1-azido-5-<(tert-butyldimethylsilyl)oxy>pentane

There total 6 articles about (S)-2--1-azido-5-<(tert-butyldimethylsilyl)oxy>pentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 132316-98-4
(S)-2--5-<(tert-butyldimethylsilyl)oxy>pentan-1-ol

: 132343-48-7
(S)-2--1-azido-5-<(tert-butyldimethylsilyl)oxy>pentane

Guidance literature:: With diphenyl phosphoryl azide; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 23 ℃; for 48h;
DOI:10.1021/jo00006a002

Reference yield:

: 77539-18-5,73914-82-6
(S)-(+)-2-benzylamino glutaric acid

: 132343-48-7
(S)-2--1-azido-5-<(tert-butyldimethylsilyl)oxy>pentane

Guidance literature:: Multi-step reaction with 4 steps

1: 71 percent / NaHCO₃ / H₂O / 3 h / Ambient temperature

2: 70 percent / BH₃*THF / tetrahydrofuran / 18 h / Ambient temperature

3: 88 percent / pyridine, DMAP / CH₂Cl₂ / 18 h / Ambient temperature

4: 83 percent / triphenylphosphine, diethyl azodicarboxylate, diphenylphosphoryl azide / tetrahydrofuran / 48 h / Ambient temperature

With pyridine; dmap; borane-THF; diphenylphosphoranyl azide; sodium hydrogencarbonate; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/jo00040a045

Reference yield:

: 132316-97-3
(S)-2--1,5-pentanediol

: 132343-48-7
(S)-2--1-azido-5-<(tert-butyldimethylsilyl)oxy>pentane

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / pyridine, DMAP / CH₂Cl₂ / 18 h / Ambient temperature

2: 83 percent / triphenylphosphine, diethyl azodicarboxylate, diphenylphosphoryl azide / tetrahydrofuran / 48 h / Ambient temperature

With pyridine; dmap; diphenylphosphoranyl azide; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00040a045