7-(4-(4,5-diphenyl-1H-imidazol-2-yl)phenyl)-1,4,10,13-tetraoxa-7-azacyclopentadecane

Base Information

• Chemical Name: 7-(4-(4,5-diphenyl-1H-imidazol-2-yl)phenyl)-1,4,10,13-tetraoxa-7-azacyclopentadecane
• CAS No.: 382145-14-4
• Molecular Formula: C₃₁H₃₅N₃O₄
• Molecular Weight: 513.637
• Mol file: 382145-14-4.mol

Synonyms:7-(4-(4,5-diphenyl-1H-imidazol-2-yl)phenyl)-1,4,10,13-tetraoxa-7-azacyclopentadecane

Chemical Property of 7-(4-(4,5-diphenyl-1H-imidazol-2-yl)phenyl)-1,4,10,13-tetraoxa-7-azacyclopentadecane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7-(4-(4,5-diphenyl-1H-imidazol-2-yl)phenyl)-1,4,10,13-tetraoxa-7-azacyclopentadecane

There total 1 articles about 7-(4-(4,5-diphenyl-1H-imidazol-2-yl)phenyl)-1,4,10,13-tetraoxa-7-azacyclopentadecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

4-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)-benzaldehyde (66749-96-0) + benzil (134-81-6) → 7-(4-(4,5-diphenyl-1H-imidazol-2-yl)phenyl)-1,4,10,13-tetraoxa-7-azacyclopentadecane (382145-14-4)

Guidance literature:

With ammonium acetate; In acetic acid; for 1h; Heating;

DOI:10.1016/S0040-4039(01)01572-6

Reference yield: 70.0%

copper(II) bis(tetrafluoroborate) + 7-(4-(4,5-diphenyl-1H-imidazol-2-yl)phenyl)-1,4,10,13-tetraoxa-7-azacyclopentadecane (382145-14-4) → (7-(4-(4,5-diphenyl-1H-imidazol-2-yl)phenyl)-1,4,10,13-tetraoxa-7-azacyclopentadecane)copper(II) tetrafluoroborate dihydrate

Guidance literature:

In ethanol; a soln. of Cu salt added to a soln. of ligand, refluxed overnight; concd. (vac.), pptd. (Et2O), centrifuged, washed (cold abs. EtOH and Et2O), dried (vac.); elem. anal.;

DOI:10.1021/ic101095y

Reference yield:

7-(4-(4,5-diphenyl-1H-imidazol-2-yl)phenyl)-1,4,10,13-tetraoxa-7-azacyclopentadecane (382145-14-4) → 4,5-diphenyl-2-[4-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)-phenyl]-4H-imidazol-4-yl hydroperoxide (382145-08-6)

Guidance literature:

With oxygen; methylene blue; In dichloromethane; at -78 ℃; for 0.5h; Irradiation;

DOI:10.1016/S0040-4039(01)01572-6

upstream raw materials:

4-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)-benzaldehyde

benzil

Downstream raw materials:

4,5-diphenyl-2-[4-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)-phenyl]-4H-imidazol-4-yl hydroperoxide

C₃₁H₃₅N₃O₆