benzyl<13C>formate

Base Information

• Chemical Name: benzyl<13C>formate
• CAS No.: 98195-34-7
• Molecular Formula: C₈H₈O₂
• Molecular Weight: 137.139
• Mol file: 98195-34-7.mol

Synonyms:benzyl<13C>formate

Chemical Property of benzyl<13C>formate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of benzyl<13C>formate

There total 4 articles about benzyl<13C>formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

sodium (13)C-formate (23102-86-5) + benzyl bromide (100-39-0) → benzyl<13C>formate (98195-34-7)

Guidance literature:

In N,N-dimethyl acetamide; at 90 ℃; for 12h;

DOI:10.1021/jo00090a006

Reference yield: 82.3%

(13C)-formic acid (1633-56-3) + benzyl bromide (100-39-0) → benzyl<13C>formate (98195-34-7)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In benzene; at 80 ℃; for 2h;

DOI:10.1021/ja00125a010

Reference yield: 66.8%

benzyl bromide (100-39-0) + potassium<13C>formate (86967-49-9) → benzyl<13C>formate (98195-34-7)

Guidance literature:

With 18-crown-6 ether; In acetonitrile; 1.) 30 min; 2.) 49 h, reflux;

DOI:10.1021/ja00309a046

upstream raw materials:

sodium ⁽¹³⁾C-formate

benzyl bromide

potassium<13C>formate

(¹³C)-formic acid

Downstream raw materials:

N-methyl-[13C]-formanilide

Refernces

• 1、 Shaffer,Morton,Hanzlik. "N-dealkylation of an N-cyclopropylamine by horseradish peroxidase. Fate of the cyclopropyl group". . p. 8502 - 8508. Retrieved 2007/10/03.
• 2、 An, Yi-Zhong,Rubin, Yves,Schaller, Christophe,McElvany, Stephen W.. "Synthesis and Characterization of Diethynylmethanobuckminsterfullerene, a Building Block for Macrocyclic and Polymeric Carbon Allotropes". . p. 2927 - 2929. Retrieved 2007/10/02.