Technology Process of tricarbonyl(η5-tetrachloro(phenylthio)cyclopentadienyl)manganese
There total 1 articles about tricarbonyl(η5-tetrachloro(phenylthio)cyclopentadienyl)manganese which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
butyl lithium;
In
diethyl ether; hexane;
under N2, addn. of a soln. of BuLi to a suspn. of Mn-complex at -75°C, centrifugating, dissolving residue in Et2O, addn. of PhSSPh, warming to room temperature with stirring; removing solvent (vac.), addn. of hexane, filtn., removing solvent (vac.), IR, (13)C-NMR;
DOI:10.1016/0022-328X(94)87051-9
