Technology Process of 6-(3-hydroxy-phenoxy)-3H-benzo[c][1,2]oxaborol-1-ol
There total 9 articles about 6-(3-hydroxy-phenoxy)-3H-benzo[c][1,2]oxaborol-1-ol which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1: caesium carbonate / N,N-dimethyl-formamide / 80 °C
2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 80 °C
3: sodium tetrahydroborate / tetrahydrofuran; methanol / 0 °C
4: hydrogenchloride
With
hydrogenchloride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium tetrahydroborate; potassium acetate; caesium carbonate;
In
tetrahydrofuran; 1,4-dioxane; methanol; N,N-dimethyl-formamide;
DOI:10.1016/j.bmcl.2011.02.024
- Guidance literature:
-
With
hydrogen;
palladium 10% on activated carbon;
In
ethyl acetate;
for 2h;
under 2585.81 Torr;
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium acetate / (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,4-dioxane / 2 h / 90 °C
2.1: sodium tetrahydroborate / tetrahydrofuran; methanol / 0.17 h / 0 °C
2.2: 0.33 h / pH 3
3.1: hydrogen / palladium 10% on activated carbon / ethyl acetate / 2 h / 2585.81 Torr
With
sodium tetrahydroborate; hydrogen; potassium acetate;
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; palladium 10% on activated carbon;
In
tetrahydrofuran; 1,4-dioxane; methanol; ethyl acetate;
