(3'aS,6'R,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<14H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxol>-8'-ol

Base Information Edit

Chemical Name:(3'aS,6'R,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<14H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxol>-8'-ol
CAS No.:132802-50-7
Molecular Formula:C₂₇H₃₈O₃S₂
Molecular Weight:474.729
Hs Code.:
Mol file:132802-50-7.mol

(3'aS,6'R,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<14H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxol>-8'-ol

Synonyms:(3'aS,6'R,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<14H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxol>-8'-ol

Suppliers and Price of (3'aS,6'R,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<14H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxol>-8'-ol

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Chemical Property of (3'aS,6'R,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<14H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxol>-8'-ol Edit

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Technology Process of (3'aS,6'R,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<14H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxol>-8'-ol

There total 2 articles about (3'aS,6'R,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<14H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxol>-8'-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 124126-53-0,132881-70-0
(4'aR,5'S,7'R,10'S,11'S,12'aR)-decahydro-4'a,13',13'-trimethylspiro<1,3-dithiolane-2,1'(2'H)-<7,10>methanobenzocyclodecene>-5',10',11'(5'H)-triol

: 100-52-7
benzaldehyde

: 132802-50-7
(3'aS,6'R,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<14H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxol>-8'-ol

Guidance literature:: With 4 A molecular sieve; toluene-4-sulfonic acid; In benzene; for 3h; Ambient temperature;
DOI:10.1021/jo00007a038

Reference yield:

: 124126-52-9,124509-65-5
C₂₀H₃₀OS₂

: 132802-50-7
(3'aS,6'R,8'S,8'aR,12'aR,13'aS)-decahydro-8'a,14',14'-trimethyl-2'-phenylspiro<1,3-dithiolane-2,12'(9'H)-<14H-3a,6>methanobenzo<4,5>cyclodeca<1,2-d><1,3>dioxol>-8'-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) osmium tetroxide, pyridine, 2.) LiAlH₄ / 1.) over night, room temperature, 2.) tetrahydrofuran, overnight

2: 85 percent / p-toluenesulfonic acid, 4 Angstroem molecular sieves / benzene / 3 h / Ambient temperature

With pyridine; osmium(VIII) oxide; lithium aluminium tetrahydride; 4 A molecular sieve; toluene-4-sulfonic acid; In benzene;
DOI:10.1021/jo00007a038