1,2-bis(diphenylphosphino)ethane-bis(triphenylphosphine)nickel⁽⁰⁾

Base Information

• Chemical Name: 1,2-bis(diphenylphosphino)ethane-bis(triphenylphosphine)nickel⁽⁰⁾
• CAS No.: 54428-80-7
• Molecular Formula: C₆₂H₅₄NiP₄
• Molecular Weight: 981.696
• Mol file: 54428-80-7.mol

Synonyms:1,2-bis(diphenylphosphino)ethane-bis(triphenylphosphine)nickel⁽⁰⁾

Chemical Property of 1,2-bis(diphenylphosphino)ethane-bis(triphenylphosphine)nickel⁽⁰⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of 1,2-bis(diphenylphosphino)ethane-bis(triphenylphosphine)nickel⁽⁰⁾

There total 7 articles about 1,2-bis(diphenylphosphino)ethane-bis(triphenylphosphine)nickel⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + triphenylphosphine (603-35-0) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → 1,2-bis(diphenylphosphino)ethane-bis(triphenylphosphine)nickel(0) (54428-80-7)

Guidance literature:

In benzene-d6; at 60 ℃;

DOI:10.1016/j.ica.2015.04.003

Reference yield:

1,2-bis(diphenylphosphino)ethane nickel(II) chloride (14647-23-5) + triphenylphosphine (603-35-0) → 1,2-bis(diphenylphosphino)ethane-bis(triphenylphosphine)nickel(0) (54428-80-7)

Guidance literature:

With ethylmagnesium bromide; In diethyl ether; 2 equiv ethylmagnesium bromide, 2 equiv oh P(C6H5)3, diethyl ether, 2 h;

DOI:10.1021/ja202877q

Reference yield:

bis(triphenylphosphine)nickel(0) dicarbonyl (13007-90-4) → 1,2-bis(diphenylphosphino)ethane-bis(triphenylphosphine)nickel(0) (54428-80-7)

Guidance literature:

Multi-step reaction with 2 steps

1: chloroform-d1 / 2 h / 55 °C / Inert atmosphere; Schlenk technique

2: benzene-d6 / 60 °C

In chloroform-d1; benzene-d6;

DOI:10.1016/j.ica.2015.04.003

upstream raw materials:

1,2-bis(diphenylphosphino)ethane nickel(II) chloride

triphenylphosphine

C₄₃H₄₀ClF₃NiO₄P₂

C₄₄H₄₃ClF₃NNiO₃P₂

Downstream raw materials:

cis-(bromo)(phenyl)[1,2-bis(diphenylphosphino)ethane]nickel

C₄₃H₄₉BrNiP₂Si