2,6-Diphenylphenol

Base Information

• Chemical Name: 2,6-Diphenylphenol
• CAS No.: 2432-11-3
• Molecular Formula: C18H14O
• Molecular Weight: 246.309
• Hs Code.: 29071990
• European Community (EC) Number: 219-401-9
• UNII: LA93W35M96
• DSSTox Substance ID: DTXSID30947151
• Nikkaji Number: J102.860J
• Wikidata: Q20898365
• Mol file: 2432-11-3.mol

Synonyms:2,6-Diphenylphenol;2432-11-3;[1,1':3',1''-Terphenyl]-2'-ol;[m-Terphenyl]-2'-ol;m-Terphenyl-2'-ol;2'-Hydroxy-m-terphenyl;MFCD00009716;LA93W35M96;(M-TERPHENYL)-2'-OL;C18H14O;2,6-diphenyl phenol;(1,1':3',1''-TERPHENYL)-2'-OL;2,6-di-phenylphenol;2,6,-Diphenylphenol;2,6-di(phenyl)phenol;SCHEMBL60283;2,6-Diphenylphenol, 98%;UNII-LA93W35M96;ATGFTMUSEPZNJD-UHFFFAOYSA-;PHENOL, 2,6-DIPHENYL-;DTXSID30947151;AMY38633;EINECS 219-401-9;AC8713;AKOS015918243;AC-30727;SY009068;3-PHENYL-[1,1'-BIPHENYL]-2-OL;CS-0156488;D2563;FT-0610721;D78169;EC 219-401-9;A817224;J-015445;Q20898365;26353-84-4

Chemical Property of 2,6-Diphenylphenol

Chemical Property:

• Appearance/Colour: White to off-white crystals or powder
• Melting Point: 101-103 °C(lit.)
• Refractive Index: 1.4700 (estimate)
• Boiling Point: 384.8 °C at 760 mmHg
• PKA: 10.02±0.10(Predicted)
• Flash Point: 183.2 °C
• PSA: 20.23000
• Density: 1.128 g/cm³
• LogP: 4.72620
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: Chloroform (Slightly), Methanol (Slightly)
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 246.104465066
• Heavy Atom Count: 19
• Complexity: 237

Purity/Quality:

99.9% ^*data from raw suppliers

2,6-Diphenylphenol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C(C(=CC=C2)C3=CC=CC=C3)O
• Uses: 2,6-Diphenylphenol has been used:as ligand during the synthesis of reduced coordination (less than 6), unchelated manganese oxygen cluster systemsin the preparation of derivatives of pyrazine-2,3-dicarbonitrile, precursor required for the synthesis of octaazaphthalocyanine (AzaPc) derivatives

Technology Process of 2,6-Diphenylphenol

There total 73 articles about 2,6-Diphenylphenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.3%

2,6-Dichlorophenol (87-65-0) + phenylboronic acid (98-80-6) → (1,1';3',1''-terphenyl)-2'-ol (2432-11-3)

Guidance literature:

With palladium diacetate; dicyclohexylphenylphosphine; In water; 1,2-dichloro-ethane; at 40 - 70 ℃; for 3h; Reagent/catalyst; Solvent; Temperature; Concentration; Inert atmosphere; Sealed tube;

Reference yield: 94.0%

3-ethoxyacrolein (19060-08-3) + 1,3-Diphenylpropanone (102-04-5) → (1,1';3',1''-terphenyl)-2'-ol (2432-11-3)

Guidance literature:

1,3-Diphenylpropanone; With sodium hydroxide; In 1,4-dioxane; at 20 ℃; for 0.5h;

3-ethoxyacrolein; In 1,4-dioxane; at 0 - 100 ℃;

Reference yield: 92.0%

2,6-Dichlorophenol (87-65-0) + triethoxyphenylsilane (780-69-8) → (1,1';3',1''-terphenyl)-2'-ol (2432-11-3)

Guidance literature:

With Pd((CH₃)2C₆H₃NC(CH₃)CHC(CH₃)NC₆H₃(CH₃)2)(CH₃)(P(CH₂CH₃)3); tetrabutylammomium bromide; sodium hydroxide; In water; at 80 ℃; for 10h; Inert atmosphere;

DOI:10.1039/c0cc03535a

upstream raw materials:

diphenylether

phenyl sodium

2,6-bis(1-cyclohexenyl)cyclohexanone

2-phenoxy-1,1'-biphenyl

Downstream raw materials:

2,6-Diphenyl-4,4'-(1-methylethylidene)bisphenol

2,2',6,6'-Tetraphenyl-4,4'-(1-methylethylidene)bisphenol

1,3-Diphenyl-2-(phenylmethoxy)benzene

[1,1';4',1'']terphenyl

Refernces

• 1、 Bosmans, Vera,Poater, Jordi,Hammink, Roel,Tinnemans, Paul,Bickelhaupt, F. Matthias,Mecinovi?, Jasmin. "Probing Through-Space Polar-π Interactions in 2,6-Diarylphenols". . . Retrieved 2019.
• 2、 Emami, Atefeh,Ghafuri, Hossein. "Synergetic catalytic effect of rGO, Pd, Fe3O4 and PPy as a magnetically separable and recyclable nanocomposite for coupling reactions in green media". . . Retrieved 2018/07/31.