hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}bis(triphenylphosphine)iridium(III) hexafluoroantimonate

Base Information

Chemical Name:hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}bis(triphenylphosphine)iridium(III) hexafluoroantimonate
CAS No.:137466-22-9
Molecular Formula:C₅₃H₄₃IrNP₂*F₆Sb
Molecular Weight:1183.84
Hs Code.:

Synonyms:hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}bis(triphenylphosphine)iridium(III) hexafluoroantimonate

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Chemical Property of hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}bis(triphenylphosphine)iridium(III) hexafluoroantimonate

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Technology Process of hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}bis(triphenylphosphine)iridium(III) hexafluoroantimonate

There total 1 articles about hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}bis(triphenylphosphine)iridium(III) hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 91410-27-4
{Ir(COD)(PPh₃)2}SbF₆

: 3558-69-8
2,6-diphenylpyridine

: 137466-22-9
hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}bis(triphenylphosphine)iridium(III) hexafluoroantimonate

Guidance literature:: With H₂; In dichloromethane; byproducts: cyclooctane; dissolving of the COD complex salt in CH2Cl2, addn. of 2,6-diphpy to the red soln., cooling (0°C), bubbling H2 through the mixt. (5 min), color change from red to yellow, evapn. of solvent to 2 ml, addn. of diethyl ether, pptn.; filtration, washing (Et2O), drying (vac.), recrystn. (CH2Cl2/Et2O); elem. anal.;
DOI:10.1021/om00037a045

Reference yield: 90.0%

: 137466-22-9
hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}bis(triphenylphosphine)iridium(III) hexafluoroantimonate

: 75-05-8,26809-02-9
acetonitrile

: 137466-36-5
hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}(acetonitrile)bis(triphenylphosphine)iridium(III) hexafluoroantimonate

Guidance literature:: In acetonitrile; dissolving of the Ir complex salt in CH3CN, stirring (room temp., 30 min), color change from yellow to colorless, evapn. of solvent to 0.5 ml, addn. of Et2O, pptn.; filtration, washing (Et2O), air-drying; elem. anal.;
DOI:10.1021/om00037a045

Reference yield: 80.0%

: 137466-22-9
hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}bis(triphenylphosphine)iridium(III) hexafluoroantimonate

: 137466-34-3
hydro{2-(6-phenyl-2-pyridinyl)phenyl-C,N}carbonylbis(triphenylphosphine)iridium(III) hexafluoroantimonate

Guidance literature:: With CO; In dichloromethane; passing CO through a soln. of the Ir complex salt in CH2Cl2 (room temp.), color change within 1 min from yellow to colorless, evapn. of solvent to 0.5 ml, addn. of cold Et2O, pptn.; filtration, washing (cold Et2O), drying (vac.); elem. anal.;
DOI:10.1021/om00037a045