Rucl2[(S)-xylbinap][(S,S)-dpen]

Base Information

• Chemical Name: Rucl2[(S)-xylbinap][(S,S)-dpen]
• CAS No.: 220114-03-4
• Molecular Formula: C₆₆H₆₄Cl₂N₂P₂Ru
• Molecular Weight: 1119.17
• European Community (EC) Number: 811-495-5
• DSSTox Substance ID: DTXSID30456435
• Mol file: 220114-03-4.mol

Synonyms:220114-03-4;RUCL2[(S)-XYLBINAP][(S,S)-DPEN];RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN];[1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;dichlororuthenium;(1S,2S)-1,2-diphenylethane-1,2-diamine;DTXSID30456435;VIA11403;MFCD09753030;SC10173;T72096;(1-{2-[bis(3,5-dimethylphenyl)phosphanyl]naphthalen-1-yl}naphthalen-2-yl)bis(3,5-dimethylphenyl)phosphane;DICHLORO[(S)-(-)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II);RUCL2[(S)-(DM-BINAP)][(S,S)-DPEN];Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II), ?RuCl2[(S)-xylbinap][(S,S)-dpen];Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II), RuCl2[(S)-xylbinap][(S,S)-dpen]

Chemical Property of Rucl2[(S)-xylbinap][(S,S)-dpen]

Chemical Property:

• PSA: 79.22000
• LogP: 9.43860
• Storage Temp.: 2-8°C
• Sensitive.: air sensitive
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 10
• Exact Mass: 1118.296520
• Heavy Atom Count: 73
• Complexity: 1170

Purity/Quality:

98%,99%, ^*data from raw suppliers

RuCl2[(S)-xylbinap][(S,S)-dpen] ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.C1=CC=C(C=C1)C(C(C2=CC=CC=C2)N)N.Cl[Ru]Cl
• Isomeric SMILES: CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.C1=CC=C(C=C1)[C@@H]([C@H](C2=CC=CC=C2)N)N.Cl[Ru]Cl
• Uses: Takasago Ligands and Complexes for Asymmetric Reactions

Technology Process of Rucl2[(S)-xylbinap][(S,S)-dpen]

There total 1 articles about Rucl2[(S)-xylbinap][(S,S)-dpen] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(R)-(+)-2,2'-bis[bis(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl + dichloro(benzene)ruthenium(II) dimer (37366-09-9) + (S,S)-1,2-diphenyl-1,2-diaminoethane (29841-69-8) → C66H64Cl2N2P2Ru (220114-03-4)

Guidance literature:

(R)-(+)-2,2'-bis[bis(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl; dichloro(benzene)ruthenium(II) dimer; In N,N-dimethyl-formamide; at 100 ℃; for 0.166667h; Glovebox; Inert atmosphere; Schlenk technique;

(S,S)-1,2-diphenyl-1,2-diaminoethane; In N,N-dimethyl-formamide; at 20 ℃; for 3h; Glovebox; Schlenk technique; Inert atmosphere;

DOI:10.1002/anie.202001561

upstream raw materials:

dichloro(benzene)ruthenium(II) dimer

(S,S)-1,2-diphenyl-1,2-diaminoethane

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