Cu(isopropyl isocyanide)(bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine)

Base Information

• Chemical Name: Cu(isopropyl isocyanide)(bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine)
• CAS No.: 1262801-82-0
• Molecular Formula: C₃₅H₄₆CuN₃
• Molecular Weight: 572.316
• Mol file: 1262801-82-0.mol

Synonyms:Cu(isopropyl isocyanide)(bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine)

Chemical Property of Cu(isopropyl isocyanide)(bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine)

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of Cu(isopropyl isocyanide)(bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine)

There total 1 articles about Cu(isopropyl isocyanide)(bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine (1218928-01-8) + [ClCu(CNiPr)]4 (1291102-96-9) → Cu(isopropyl isocyanide)(bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine) (1262801-82-0)

Guidance literature:

With lithium hexamethyldisilylamide; In tetrahydrofuran; (under Ar, Schlenk); Li-salt and ligand in THF stirred for 1 h, Cu-complex in THF added, stirred for 16 h; volatiles removed under reduced pressure, hexane added, stirred for 15 min, volatiles removed under reduced pressure, hexane added, filtered, volatiles removed in vacuo, recrystd. from hexane at -40°C; elem. anal.;

DOI:10.1021/ic101524b

upstream raw materials:

bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine

[ClCu(CNⁱPr)]₄