bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine

Base Information

• Chemical Name: bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine
• CAS No.: 1218928-01-8
• Molecular Formula: C₃₁H₄₀N₂
• Molecular Weight: 440.672
• Mol file: 1218928-01-8.mol

Synonyms:bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine

Chemical Property of bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine

There total 1 articles about bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) + 6-dimethylaminofulvene-1-(N,N-dimethyl)formaldimonium chloride → bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine (1218928-01-8)

Guidance literature:

In ethanol; for 16h; Reflux;

DOI:10.1021/ic101524b

Reference yield: 64.0%

bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine (1218928-01-8) + [ClCu(CNiPr)]4 (1291102-96-9) → Cu(isopropyl isocyanide)(bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine) (1262801-82-0)

Guidance literature:

With lithium hexamethyldisilylamide; In tetrahydrofuran; (under Ar, Schlenk); Li-salt and ligand in THF stirred for 1 h, Cu-complex in THF added, stirred for 16 h; volatiles removed under reduced pressure, hexane added, stirred for 15 min, volatiles removed under reduced pressure, hexane added, filtered, volatiles removed in vacuo, recrystd. from hexane at -40°C; elem. anal.;

DOI:10.1021/ic101524b

Reference yield: 36.0%

bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine (1218928-01-8) + trimethylaluminum (75-24-1) → AlMe2(bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine) (1262801-84-2)

Guidance literature:

In tetrahydrofuran; toluene; (under Ar, Schlenk); THF added to ligand, soln. of Al(CH3)3 in toluene added, stirred for 16 h; filtered, volatiles removed in vacuo, stored at -28°C; elem. anal.;

DOI:10.1021/ic101524b

upstream raw materials:

2,6-diisopropylbenzenamine

Downstream raw materials:

AlMe₂(bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine)

Cu(isopropyl isocyanide)(bis(N,N'-2,6-diisopropylphenyl)-6-aminofulvene-2-aldimine)