Tert-butyldimethylphosphine

Base Information

Chemical Name:Tert-butyldimethylphosphine
CAS No.:32376-17-3
Molecular Formula:C₆H₁₅P
Molecular Weight:118.159
Hs Code.:2901100000
DSSTox Substance ID:DTXSID50463247
Nikkaji Number:J1.388.027A
Mol file:32376-17-3.mol

Synonyms:TERT-BUTYLDIMETHYLPHOSPHINE;tert-butyl(dimethyl)phosphane;32376-17-3;t-Butyldimethylphosphine;SCHEMBL1743241;DTXSID50463247;MFCD17170380

Suppliers and Price of Tert-butyldimethylphosphine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Tert-butyldimethylphosphine

Chemical Property:

PSA：13.59000
LogP:2.52640
XLogP3:0.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:118.091137476
Heavy Atom Count:7
Complexity:49.7

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)P(C)C

Technology Process of Tert-butyldimethylphosphine

There total 4 articles about Tert-butyldimethylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 917-54-4
methyllithium

: 25979-07-1
tert-butyldichlorophosphine

: 32376-17-3
dimethyl-t-butylphosphine

Guidance literature:: In diethyl ether; at -78 - 20 ℃; for 12.3333h; Inert atmosphere;
DOI:10.1002/ejic.201101098

Reference yield:

: 75-16-1
methylmagnesium bromide

: 25979-07-1
tert-butyldichlorophosphine

: 32376-17-3
dimethyl-t-butylphosphine

Guidance literature:: In tetrahydrofuran; diethyl ether; at -10 - 20 ℃; Inert atmosphere;
DOI:10.1039/b806864j DOI:10.1021/ol800109s

Reference yield:

: (R)-tert-butyl(2-methyl-2-phenyl-2-sila-1-propyl)methylphosphine-P-borane

: 32376-17-3
dimethyl-t-butylphosphine

: C₁₄H₂₅PSi

Guidance literature:: (R)-tert-butyl(2-methyl-2-phenyl-2-sila-1-propyl)methylphosphine-P-borane; With tetrafluoroboric acid diethyl ether; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

With sodium hydrogencarbonate; In dichloromethane; water; for 1h; Inert atmosphere; Schlenk technique;
DOI:10.1021/om3012294